Abstract
Various aryl 6-deoxy-5-keto-ß-D-arabino-hexofuranosides, including one (42) corresponding to the sugar-cinnamate unit of Hygromycin A (1) have been synthesized by a method in which 6-deoxy-ß-D-glucofuranosides are first prepared, followed by configurational inversion at positions 2 and 3 via 2,3-anhydro-6-deoxy-ß-D-mannofuranosyl intermediates.
Original language | English |
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Pages (from-to) | 6033-6050 |
Number of pages | 18 |
Journal | Tetrahedron |
Volume | 51 |
Issue number | 21 |
DOIs | |
Publication status | Published - 1995 |