A stable NH4PO3-glass proton conductor for intermediate temperature fuel cells

Yinzhu Jiang; Teci Matthieu; Rong Lan; Xiaoxiang Xu; Peter Ian Cowin; Shanwen Tao

doi:10.1016/j.ssi.2010.11.028

A stable NH₄PO₃-glass proton conductor for intermediate temperature fuel cells

Yinzhu Jiang, Teci Matthieu, Rong Lan, Xiaoxiang Xu, Peter Ian Cowin, Shanwen Tao

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

A stable and conductive composite material based on NH₄PO₃ and amorphous oxides (SiO₂-P₂O₅) has been prepared by a wet-chemical route following with firing in ammonia. The composite showed high proton conductivity in both ambient air and humidified 5% H₂/Ar. A total conductivity of 6.0-19 mS/cm in the temperature range of 150-250 °C has been achieved. The conductivity (about 19 mS/cm) is stable in humidified 5% H₂/Ar during ageing at 175 °C for over 100 h. This material is a potential electrolyte for intermediate temperature fuel cells and other electrochemical devices. © 2010.

Original language	English
Pages (from-to)	108-112
Number of pages	5
Journal	Solid State Ionics
Volume	192
Issue number	1
Early online date	21 Dec 2010
DOIs	https://doi.org/10.1016/j.ssi.2010.11.028
Publication status	Published - 16 Jun 2011

Keywords

Conductivity
NH 4 PO 3
Proton conductor

Access to Document

10.1016/j.ssi.2010.11.028

Cite this

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title = "A stable NH4PO3-glass proton conductor for intermediate temperature fuel cells",

abstract = "A stable and conductive composite material based on NH4PO3 and amorphous oxides (SiO2-P2O5) has been prepared by a wet-chemical route following with firing in ammonia. The composite showed high proton conductivity in both ambient air and humidified 5\% H2/Ar. A total conductivity of 6.0-19 mS/cm in the temperature range of 150-250 °C has been achieved. The conductivity (about 19 mS/cm) is stable in humidified 5\% H2/Ar during ageing at 175 °C for over 100 h. This material is a potential electrolyte for intermediate temperature fuel cells and other electrochemical devices. {\textcopyright} 2010.",

keywords = "Conductivity, NH 4 PO 3, Proton conductor",

author = "Yinzhu Jiang and Teci Matthieu and Rong Lan and Xiaoxiang Xu and Cowin, \{Peter Ian\} and Shanwen Tao",

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doi = "10.1016/j.ssi.2010.11.028",

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T1 - A stable NH4PO3-glass proton conductor for intermediate temperature fuel cells

AU - Jiang, Yinzhu

AU - Matthieu, Teci

AU - Lan, Rong

AU - Xu, Xiaoxiang

AU - Cowin, Peter Ian

AU - Tao, Shanwen

PY - 2011/6/16

Y1 - 2011/6/16

N2 - A stable and conductive composite material based on NH4PO3 and amorphous oxides (SiO2-P2O5) has been prepared by a wet-chemical route following with firing in ammonia. The composite showed high proton conductivity in both ambient air and humidified 5% H2/Ar. A total conductivity of 6.0-19 mS/cm in the temperature range of 150-250 °C has been achieved. The conductivity (about 19 mS/cm) is stable in humidified 5% H2/Ar during ageing at 175 °C for over 100 h. This material is a potential electrolyte for intermediate temperature fuel cells and other electrochemical devices. © 2010.

AB - A stable and conductive composite material based on NH4PO3 and amorphous oxides (SiO2-P2O5) has been prepared by a wet-chemical route following with firing in ammonia. The composite showed high proton conductivity in both ambient air and humidified 5% H2/Ar. A total conductivity of 6.0-19 mS/cm in the temperature range of 150-250 °C has been achieved. The conductivity (about 19 mS/cm) is stable in humidified 5% H2/Ar during ageing at 175 °C for over 100 h. This material is a potential electrolyte for intermediate temperature fuel cells and other electrochemical devices. © 2010.

KW - Conductivity

KW - NH 4 PO 3

KW - Proton conductor

U2 - 10.1016/j.ssi.2010.11.028

DO - 10.1016/j.ssi.2010.11.028

M3 - Article

SN - 0167-2738

VL - 192

SP - 108

EP - 112

JO - Solid State Ionics

JF - Solid State Ionics

IS - 1