A Solution-processable Dissymmetric Porous Organic Cage

Anna Grace Slater; Marc A.  Little; Michael E. Briggs; Kim E. Jelfs; Andrew I. Cooper

doi:10.1039/c7me00090a

A Solution-processable Dissymmetric Porous Organic Cage

Anna Grace Slater^*, Marc A. Little, Michael E. Briggs, Kim E. Jelfs, Andrew I. Cooper

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

Two dissymmetric racemic analogues of the chiral porous organic cage, CC3, were isolated and unambiguously characterised as a racemate pair of the R,R,R,S,S,S and S,S,S,R,R,R-diastereomers (CC3-RS and CC3-SR). CC3-RS/CC3-SR equals the highest porosity measured for CC3 but is an order of magnitude more soluble, making it an excellent candidate for incorporation into a membrane for separation applications.

Original language	English
Pages (from-to)	223-227
Number of pages	5
Journal	Molecular Systems Design and Engineering
Volume	3
Issue number	1
DOIs	https://doi.org/10.1039/c7me00090a
Publication status	Published - 28 Feb 2018

ASJC Scopus subject areas

Chemistry (miscellaneous)
Chemical Engineering (miscellaneous)
Biomedical Engineering
Energy Engineering and Power Technology
Process Chemistry and Technology
Industrial and Manufacturing Engineering
Materials Chemistry

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title = "A Solution-processable Dissymmetric Porous Organic Cage",

abstract = "Two dissymmetric racemic analogues of the chiral porous organic cage, CC3, were isolated and unambiguously characterised as a racemate pair of the R,R,R,S,S,S and S,S,S,R,R,R-diastereomers (CC3-RS and CC3-SR). CC3-RS/CC3-SR equals the highest porosity measured for CC3 but is an order of magnitude more soluble, making it an excellent candidate for incorporation into a membrane for separation applications.",

author = "Slater, {Anna Grace} and Little, {Marc A.} and Briggs, {Michael E.} and Jelfs, {Kim E.} and Cooper, {Andrew I.}",

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AU - Slater, Anna Grace

AU - Little, Marc A.

AU - Briggs, Michael E.

AU - Jelfs, Kim E.

AU - Cooper, Andrew I.

PY - 2018/2/28

Y1 - 2018/2/28

N2 - Two dissymmetric racemic analogues of the chiral porous organic cage, CC3, were isolated and unambiguously characterised as a racemate pair of the R,R,R,S,S,S and S,S,S,R,R,R-diastereomers (CC3-RS and CC3-SR). CC3-RS/CC3-SR equals the highest porosity measured for CC3 but is an order of magnitude more soluble, making it an excellent candidate for incorporation into a membrane for separation applications.

AB - Two dissymmetric racemic analogues of the chiral porous organic cage, CC3, were isolated and unambiguously characterised as a racemate pair of the R,R,R,S,S,S and S,S,S,R,R,R-diastereomers (CC3-RS and CC3-SR). CC3-RS/CC3-SR equals the highest porosity measured for CC3 but is an order of magnitude more soluble, making it an excellent candidate for incorporation into a membrane for separation applications.

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U2 - 10.1039/c7me00090a

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JF - Molecular Systems Design and Engineering

IS - 1

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A Solution-processable Dissymmetric Porous Organic Cage

Abstract

ASJC Scopus subject areas

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