A single crystalline porphyrinic titanium metal-organic framework

Shuai Yuan; Tian-Fu Liu; Dawei Feng; Jian Tian; Kecheng Wang; Junsheng Qin; Qiang Zhang; Ying-Pin Chen; Mathieu Bosch; Lanfang Zou; Simon J. Teat; Scott J. Dalgarno; Hong-Cai Zhou

doi:10.1039/c5sc00916b

A single crystalline porphyrinic titanium metal-organic framework

Shuai Yuan, Tian-Fu Liu, Dawei Feng, Jian Tian, Kecheng Wang, Junsheng Qin, Qiang Zhang, Ying-Pin Chen, Mathieu Bosch, Lanfang Zou, Simon J. Teat, Scott J. Dalgarno, Hong-Cai Zhou^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

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Abstract

We successfully assembled the photocatalytic titanium-oxo cluster and photosensitizing porphyrinic linker into a metal-organic framework (MOF), namely PCN-22. A preformed titanium-oxo carboxylate cluster is adopted as the starting material to judiciously control the MOF growth process to afford single crystals. This synthetic method is useful to obtain highly crystalline titanium MOFs, which has been a daunting challenge in this field. Moreover, PCN-22 demonstrated permanent porosity and photocatalytic activities toward alcohol oxidation.

Original language	English
Pages (from-to)	3926-3930
Number of pages	5
Journal	Chemical Science
Volume	6
Issue number	7
DOIs	https://doi.org/10.1039/c5sc00916b
Publication status	Published - 1 Jul 2015

Keywords

FUNCTIONAL-GROUPS
CARBON-DIOXIDE
PHOTOCATALYSIS
TIO2
EFFICIENT
CATALYST

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Scott J. Dalgarno
- s.j.dalgarnohw.acuk
- School of Engineering & Physical Sciences - Professor
- School of Engineering & Physical Sciences, Institute of Chemical Sciences - Professor
Person: Academic (Research & Teaching)

Cite this

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title = "A single crystalline porphyrinic titanium metal-organic framework",

abstract = "We successfully assembled the photocatalytic titanium-oxo cluster and photosensitizing porphyrinic linker into a metal-organic framework (MOF), namely PCN-22. A preformed titanium-oxo carboxylate cluster is adopted as the starting material to judiciously control the MOF growth process to afford single crystals. This synthetic method is useful to obtain highly crystalline titanium MOFs, which has been a daunting challenge in this field. Moreover, PCN-22 demonstrated permanent porosity and photocatalytic activities toward alcohol oxidation.",

keywords = "FUNCTIONAL-GROUPS, CARBON-DIOXIDE, PHOTOCATALYSIS, TIO2, EFFICIENT, CATALYST",

author = "Shuai Yuan and Tian-Fu Liu and Dawei Feng and Jian Tian and Kecheng Wang and Junsheng Qin and Qiang Zhang and Ying-Pin Chen and Mathieu Bosch and Lanfang Zou and Teat, {Simon J.} and Dalgarno, {Scott J.} and Hong-Cai Zhou",

note = "{"}The photophysical studies of this research was supported by the Center for Gas Separations Relevant to Clean Energy Technologies, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award Number DE-SC0001015. Structural analyses were supported by Office of Naval Research under Award Number N000141310753. The Advanced Light Source is supported by the Director, Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy under contract no. DE-AC02-05CH11231. The authors also acknowledge the financial supports of ARPA-e project funded by the U.S. Department of Energy under Award Number DE-AR0000249 and Welch Foundation under Award Number A-1725.{"}",

year = "2015",

month = jul,

day = "1",

doi = "10.1039/c5sc00916b",

language = "English",

volume = "6",

pages = "3926--3930",

journal = "Chemical Science",

issn = "2041-6520",

publisher = "Royal Society of Chemistry",

number = "7",

}

TY - JOUR

T1 - A single crystalline porphyrinic titanium metal-organic framework

AU - Yuan, Shuai

AU - Liu, Tian-Fu

AU - Feng, Dawei

AU - Tian, Jian

AU - Wang, Kecheng

AU - Qin, Junsheng

AU - Zhang, Qiang

AU - Chen, Ying-Pin

AU - Bosch, Mathieu

AU - Zou, Lanfang

AU - Teat, Simon J.

AU - Dalgarno, Scott J.

AU - Zhou, Hong-Cai

N1 - "The photophysical studies of this research was supported by the Center for Gas Separations Relevant to Clean Energy Technologies, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award Number DE-SC0001015. Structural analyses were supported by Office of Naval Research under Award Number N000141310753. The Advanced Light Source is supported by the Director, Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy under contract no. DE-AC02-05CH11231. The authors also acknowledge the financial supports of ARPA-e project funded by the U.S. Department of Energy under Award Number DE-AR0000249 and Welch Foundation under Award Number A-1725."

PY - 2015/7/1

Y1 - 2015/7/1

N2 - We successfully assembled the photocatalytic titanium-oxo cluster and photosensitizing porphyrinic linker into a metal-organic framework (MOF), namely PCN-22. A preformed titanium-oxo carboxylate cluster is adopted as the starting material to judiciously control the MOF growth process to afford single crystals. This synthetic method is useful to obtain highly crystalline titanium MOFs, which has been a daunting challenge in this field. Moreover, PCN-22 demonstrated permanent porosity and photocatalytic activities toward alcohol oxidation.

AB - We successfully assembled the photocatalytic titanium-oxo cluster and photosensitizing porphyrinic linker into a metal-organic framework (MOF), namely PCN-22. A preformed titanium-oxo carboxylate cluster is adopted as the starting material to judiciously control the MOF growth process to afford single crystals. This synthetic method is useful to obtain highly crystalline titanium MOFs, which has been a daunting challenge in this field. Moreover, PCN-22 demonstrated permanent porosity and photocatalytic activities toward alcohol oxidation.

KW - FUNCTIONAL-GROUPS

KW - CARBON-DIOXIDE

KW - PHOTOCATALYSIS

KW - TIO2

KW - EFFICIENT

KW - CATALYST

U2 - 10.1039/c5sc00916b

DO - 10.1039/c5sc00916b

M3 - Article

C2 - 29218163

SN - 2041-6520

VL - 6

SP - 3926

EP - 3930

JO - Chemical Science

JF - Chemical Science

IS - 7

ER -

A single crystalline porphyrinic titanium metal-organic framework

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Scott J. Dalgarno

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