@article{aded2f046f65458a86a74715d56bfcac,
title = "A rutheniumcis-dihydride with 2-phosphinophosphinine ligands catalyses the acceptorless dehydrogenation of benzyl alcohol",
abstract = "The first ruthenium dihydride complex featuring a phosphinine ligandcis-[Ru(H)2(2-PPh2-3-Me-6-SiMe3-PC5H2)2] was synthesised exclusively as thecis-isomer. When formedin situfrom the reaction ofcis-[Ru(Cl)2(2-PPh2-3-Me-6-SiMe3-PC5H2)2] with two equivalents of Na[BHEt3], as demonstrated by31P and1H NMR spectroscopy, the catalysed acceptorless dehydrogenation of benzyl alcohol was observed leading to benzyl benzoate in up to 70% yield.",
author = "Trodden, {Elizabeth C.} and Delve, {Matthew P.} and Christian Luz and Newland, {Robert J.} and Andresen, {John M.} and Mansell, {Stephen M.}",
note = "Funding Information: The authors thank the UK National Mass Spectrometry Facility at Swansea University for sample analysis and the Engineering and Physical Sciences Research Council and the EPSRC Centre for Doctoral Training in Critical Resource Catalysis (CRITICAT) for financial support [E. C. T.; grant code: EP/L016419/1]. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021.",
year = "2021",
month = oct,
day = "14",
doi = "10.1039/d1dt02508b",
language = "English",
volume = "50",
pages = "13407--13411",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "38",
}