A new one-dimensional coordination polymer [Co(CCl3COO) 2(CH3OH)2(μ-4,4′-bipy)]n: Synthesis and structural aspects

Pritha Talukder, Amitabha Datta, Samiran Mitra, Georgina Rosair

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

A new one-dimensional coordination polymer [Co(CCl3COO) 2(CH3OH)2(µ-4,4'-bipy)]n (1), has been synthesised and its crystal structure determined by single-crystal X-ray diffraction. The structure consists of a one-dimensional linear chain of cobalt(II) centres linked by bridging 4,4'-bipyridine units. The Co(II) ion lies at an inversion centre forming an elongated octahedral coordination sphere. There is an intramolecular hydrogen bond [2.02(5) Å] between a trichloroacetate oxygen and a methanolic hydrogen forming a planar six-membered ring.

Original languageEnglish
Pages (from-to)33-36
Number of pages4
JournalZeitschrift für Naturforschung B
Volume60
Issue number1
Publication statusPublished - Jan 2005

Keywords

  • 1D-Coordination Polymer
  • 4-4′-Bipyridine
  • Cobalt(II)
  • Crystal Structure

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