A new one-dimensional coordination polymer [Co(CCl3COO) 2(CH3OH)2(μ-4,4′-bipy)]n: Synthesis and structural aspects

Pritha Talukder; Amitabha Datta; Samiran Mitra; Georgina Rosair

A new one-dimensional coordination polymer [Co(CCl₃COO) ₂(CH₃OH)₂(μ-4,4′-bipy)]_n: Synthesis and structural aspects

Pritha Talukder, Amitabha Datta, Samiran Mitra, Georgina Rosair

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

A new one-dimensional coordination polymer [Co(CCl₃COO) ₂(CH₃OH)₂(µ-4,4'-bipy)]_n (1), has been synthesised and its crystal structure determined by single-crystal X-ray diffraction. The structure consists of a one-dimensional linear chain of cobalt(II) centres linked by bridging 4,4'-bipyridine units. The Co(II) ion lies at an inversion centre forming an elongated octahedral coordination sphere. There is an intramolecular hydrogen bond [2.02(5) Å] between a trichloroacetate oxygen and a methanolic hydrogen forming a planar six-membered ring.

Original language	English
Pages (from-to)	33-36
Number of pages	4
Journal	Zeitschrift für Naturforschung B
Volume	60
Issue number	1
Publication status	Published - Jan 2005

Keywords

1D-Coordination Polymer
4-4′-Bipyridine
Cobalt(II)
Crystal Structure

Cite this

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abstract = "A new one-dimensional coordination polymer [Co(CCl3COO) 2(CH3OH)2(µ-4,4'-bipy)]n (1), has been synthesised and its crystal structure determined by single-crystal X-ray diffraction. The structure consists of a one-dimensional linear chain of cobalt(II) centres linked by bridging 4,4'-bipyridine units. The Co(II) ion lies at an inversion centre forming an elongated octahedral coordination sphere. There is an intramolecular hydrogen bond [2.02(5) {\AA}] between a trichloroacetate oxygen and a methanolic hydrogen forming a planar six-membered ring.",

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T1 - A new one-dimensional coordination polymer [Co(CCl3COO) 2(CH3OH)2(μ-4,4′-bipy)]n

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AU - Talukder, Pritha

AU - Datta, Amitabha

AU - Mitra, Samiran

AU - Rosair, Georgina

PY - 2005/1

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N2 - A new one-dimensional coordination polymer [Co(CCl3COO) 2(CH3OH)2(µ-4,4'-bipy)]n (1), has been synthesised and its crystal structure determined by single-crystal X-ray diffraction. The structure consists of a one-dimensional linear chain of cobalt(II) centres linked by bridging 4,4'-bipyridine units. The Co(II) ion lies at an inversion centre forming an elongated octahedral coordination sphere. There is an intramolecular hydrogen bond [2.02(5) Å] between a trichloroacetate oxygen and a methanolic hydrogen forming a planar six-membered ring.

AB - A new one-dimensional coordination polymer [Co(CCl3COO) 2(CH3OH)2(µ-4,4'-bipy)]n (1), has been synthesised and its crystal structure determined by single-crystal X-ray diffraction. The structure consists of a one-dimensional linear chain of cobalt(II) centres linked by bridging 4,4'-bipyridine units. The Co(II) ion lies at an inversion centre forming an elongated octahedral coordination sphere. There is an intramolecular hydrogen bond [2.02(5) Å] between a trichloroacetate oxygen and a methanolic hydrogen forming a planar six-membered ring.

KW - 1D-Coordination Polymer

KW - 4-4′-Bipyridine

KW - Cobalt(II)

KW - Crystal Structure

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EP - 36

JO - Zeitschrift für Naturforschung B

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A new one-dimensional coordination polymer [Co(CCl₃COO) ₂(CH₃OH)₂(μ-4,4′-bipy)]_n: Synthesis and structural aspects

Abstract

Keywords

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