A new Cu(II) bridging-carboxylate helical chain polymer: Synthesis and structural aspects

Amitabha Datta, Dilip Kumar Dey, Wen S. Hwang, Takayuki Matsushita, Georgina Rosair

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Abstract

The crystal structure of a new Cu(II) carboxylato-bridged complex [Cu(L)(SCN)]n (1) [where HL = 2-N-(2'-pyridylimine)benzoic acid] forms a helical chain polymer chain. In 1, adjacent copper atoms are linked by carboxylate groups in a syn-anti conformation. The title complex was also characterised by elemental analysis, IR spectra, electronic spectra and variable temperature magnetic measurements.

Original languageEnglish
Pages (from-to)502-504
Number of pages3
JournalJournal of Chemical Research
Issue number8
Publication statusPublished - Aug 2005

Keywords

  • Carboxylato-bridged
  • Crystal structure
  • Helical chain polymer
  • Magnetic studies
  • Tridentate Schiff base

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    Datta, A., Dey, D. K., Hwang, W. S., Matsushita, T., & Rosair, G. (2005). A new Cu(II) bridging-carboxylate helical chain polymer: Synthesis and structural aspects. Journal of Chemical Research, (8), 502-504.