A new Cu(II) bridging-carboxylate helical chain polymer: Synthesis and structural aspects

Amitabha Datta; Dilip Kumar Dey; Wen S. Hwang; Takayuki Matsushita; Georgina Rosair

A new Cu(II) bridging-carboxylate helical chain polymer: Synthesis and structural aspects

Amitabha Datta, Dilip Kumar Dey, Wen S. Hwang, Takayuki Matsushita, Georgina Rosair

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The crystal structure of a new Cu(II) carboxylato-bridged complex [Cu(L)(SCN)]_n (1) [where HL = 2-N-(2'-pyridylimine)benzoic acid] forms a helical chain polymer chain. In 1, adjacent copper atoms are linked by carboxylate groups in a syn-anti conformation. The title complex was also characterised by elemental analysis, IR spectra, electronic spectra and variable temperature magnetic measurements.

Original language	English
Pages (from-to)	502-504
Number of pages	3
Journal	Journal of Chemical Research
Issue number	8
Publication status	Published - Aug 2005

Keywords

Carboxylato-bridged
Crystal structure
Helical chain polymer
Magnetic studies
Tridentate Schiff base

Cite this

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title = "A new Cu(II) bridging-carboxylate helical chain polymer: Synthesis and structural aspects",

abstract = "The crystal structure of a new Cu(II) carboxylato-bridged complex [Cu(L)(SCN)]n (1) [where HL = 2-N-(2'-pyridylimine)benzoic acid] forms a helical chain polymer chain. In 1, adjacent copper atoms are linked by carboxylate groups in a syn-anti conformation. The title complex was also characterised by elemental analysis, IR spectra, electronic spectra and variable temperature magnetic measurements.",

keywords = "Carboxylato-bridged, Crystal structure, Helical chain polymer, Magnetic studies, Tridentate Schiff base",

author = "Amitabha Datta and Dey, {Dilip Kumar} and Hwang, {Wen S.} and Takayuki Matsushita and Georgina Rosair",

year = "2005",

month = aug,

language = "English",

pages = "502--504",

journal = "Journal of Chemical Research",

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publisher = "Science Reviews Ltd",

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T1 - A new Cu(II) bridging-carboxylate helical chain polymer

T2 - Synthesis and structural aspects

AU - Datta, Amitabha

AU - Dey, Dilip Kumar

AU - Hwang, Wen S.

AU - Matsushita, Takayuki

AU - Rosair, Georgina

PY - 2005/8

Y1 - 2005/8

N2 - The crystal structure of a new Cu(II) carboxylato-bridged complex [Cu(L)(SCN)]n (1) [where HL = 2-N-(2'-pyridylimine)benzoic acid] forms a helical chain polymer chain. In 1, adjacent copper atoms are linked by carboxylate groups in a syn-anti conformation. The title complex was also characterised by elemental analysis, IR spectra, electronic spectra and variable temperature magnetic measurements.

AB - The crystal structure of a new Cu(II) carboxylato-bridged complex [Cu(L)(SCN)]n (1) [where HL = 2-N-(2'-pyridylimine)benzoic acid] forms a helical chain polymer chain. In 1, adjacent copper atoms are linked by carboxylate groups in a syn-anti conformation. The title complex was also characterised by elemental analysis, IR spectra, electronic spectra and variable temperature magnetic measurements.

KW - Carboxylato-bridged

KW - Crystal structure

KW - Helical chain polymer

KW - Magnetic studies

KW - Tridentate Schiff base

UR - http://www.scopus.com/inward/record.url?scp=24744453949&partnerID=8YFLogxK

M3 - Article

SN - 1747-5198

SP - 502

EP - 504

JO - Journal of Chemical Research

JF - Journal of Chemical Research

IS - 8

ER -

A new Cu(II) bridging-carboxylate helical chain polymer: Synthesis and structural aspects

Abstract

Keywords

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