A new crystalline form of 1-phenyl-1,2-dicarba-closo-dodecaborane(12)

Rhodri Ll Thomas; Georgina M. Rosair; Alan J. Welch

A new crystalline form of 1-phenyl-1,2-dicarba-closo-dodecaborane(12)

Rhodri Ll Thomas, Georgina M. Rosair, Alan J. Welch

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

A new polymorph of the title compound, C₈H₁₆B₁₀, is reported. The carborane icosahedron is relatively undistorted, with the phenyl substituent twisted out of the C2-C1-C_ring plane by 18.3(2)°, which is in good agreement with the conformation predicted by molecular-orbital calculations.

Original language	English
Pages (from-to)	1024-1026
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	52
Issue number	4
Publication status	Published - 15 Apr 1996

Cite this

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title = "A new crystalline form of 1-phenyl-1,2-dicarba-closo-dodecaborane(12)",

abstract = "A new polymorph of the title compound, C8H16B10, is reported. The carborane icosahedron is relatively undistorted, with the phenyl substituent twisted out of the C2-C1-Cring plane by 18.3(2)°, which is in good agreement with the conformation predicted by molecular-orbital calculations.",

author = "Thomas, {Rhodri Ll} and Rosair, {Georgina M.} and Welch, {Alan J.}",

year = "1996",

month = apr,

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language = "English",

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pages = "1024--1026",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

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publisher = "International Union of Crystallography",

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T1 - A new crystalline form of 1-phenyl-1,2-dicarba-closo-dodecaborane(12)

AU - Thomas, Rhodri Ll

AU - Rosair, Georgina M.

AU - Welch, Alan J.

PY - 1996/4/15

Y1 - 1996/4/15

N2 - A new polymorph of the title compound, C8H16B10, is reported. The carborane icosahedron is relatively undistorted, with the phenyl substituent twisted out of the C2-C1-Cring plane by 18.3(2)°, which is in good agreement with the conformation predicted by molecular-orbital calculations.

AB - A new polymorph of the title compound, C8H16B10, is reported. The carborane icosahedron is relatively undistorted, with the phenyl substituent twisted out of the C2-C1-Cring plane by 18.3(2)°, which is in good agreement with the conformation predicted by molecular-orbital calculations.

UR - http://www.scopus.com/inward/record.url?scp=0030122658&partnerID=8YFLogxK

M3 - Article

SN - 0108-2701

VL - 52

SP - 1024

EP - 1026

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 4

ER -

A new crystalline form of 1-phenyl-1,2-dicarba-closo-dodecaborane(12)

Abstract

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