A New and Versatile Chelating Dithio Ligand: X-ray crystal structure of [Ru(CO)(SC6H3Me-o-SC6H4Me)(η- C5H5)]

Stephen D. Killops, Selby A. R. Knox, Geoffrey H. Riding, Alan J. Welch

Research output: Contribution to journalArticle

Abstract

Under u.v. radiation diaryl disulphides (C6H4-p-R) 2S2 (R = H or Me) yield (C6H 3R-o-SC6H4R)2S2, which reacts with a variety of transition metal complexes to provide metallacycles [graphic omitted]C6H4R; one of these [Ru(CO)(SC 6H3Me-o-SC6H4Me)(η-C 5H5)], has been structurally identified by X-ray diffraction.

Original languageEnglish
Pages (from-to)486-488
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number11
DOIs
Publication statusPublished - 1978

ASJC Scopus subject areas

  • Molecular Medicine

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