A highly reactive rhodium(I)-boryl complex as a useful tool for C-H bond activation and catalytic C-F bond borylation

Michael Teltewskoi, Julien A. Panetier, Stuart A. Macgregor, Thomas Braun

Research output: Contribution to journalArticle

129 Citations (Scopus)

Abstract

Chemical Equation Presentation C-F bond borylation: A 16-electron rhodium (1)-boryl complex was synthesized by borylation of a rhodium (1)-fluorine complex. The former reacts with benzene or 2,3,5,6-tetrafluoropyridine by C-H activation. A catalytic C-F borylation reaction of pentafluoropyridine was also developed, which uses [Rh(Bpin) (PEt3)3] as a catalyst and Me3SiSiMe3 as a solvent. pin = pinacol. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Original languageEnglish
Pages (from-to)3947-3951
Number of pages5
JournalAngewandte Chemie International Edition
Volume49
Issue number23
DOIs
Publication statusPublished - 25 May 2010

Keywords

  • Boryl ligands
  • Borylation
  • C-F activation
  • C-H activation
  • Rhodium

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