A heterometallic polymeric complex: [Cu2(N3) 2(medpt)2{Ni(CN)4}]n[medpt is bis(3-aminopropyl)methylamine]1

Debajyoti Ghoshal; Tapas Kumar Maji; Georgina Rosair; Golam Mostafa

doi:10.1107/S0108270104007152

A heterometallic polymeric complex: [Cu₂(N₃) ₂(medpt)₂{Ni(CN)₄}]_n[medpt is bis(3-aminopropyl)methylamine]¹

Debajyoti Ghoshal
, Tapas Kumar Maji
, Georgina Rosair
, Golam Mostafa

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

The structure of the title compound, catena-poly[[di-µ-azido-k ⁴N¹l:N ¹-bis[[bis(3-aminopropyl)methylamine-k ³N]copper(II)]]-µ-cyano-[dicyanonickel(II)]-µ-cyano], [Cu ₂(N₃)₂(medpt)₂{Ni-(CN) ₄}]_n [medpt is bis(3-aminopropyl)methylamine, C ₇H₁₉-N₂] or [Cu₂Ni(CN) ₄(N₃)₂(C₇H₁₉N ₃)₂]_n, is a one-dimensional heterometallic covalent chain where Ni(CN)₄^2- functions as a molecular ion bridge. The Ni atom sits on the centre of inversion. The chain undergoes hydrogen-bonding interactions, forming a three-dimensional supramolecular network.

Original language	English
Pages (from-to)	m212-m214
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	60
Issue number	5
DOIs	https://doi.org/10.1107/S0108270104007152
Publication status	Published - May 2004

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title = "A heterometallic polymeric complex: [Cu2(N3) 2(medpt)2\{Ni(CN)4\}]n[medpt is bis(3-aminopropyl)methylamine]1",

abstract = "The structure of the title compound, catena-poly[[di-µ-azido-k 4N1l:N 1-bis[[bis(3-aminopropyl)methylamine-k 3N]copper(II)]]-µ-cyano-[dicyanonickel(II)]-µ-cyano], [Cu 2(N3)2(medpt)2\{Ni-(CN) 4\}]n [medpt is bis(3-aminopropyl)methylamine, C 7H19-N2] or [Cu2Ni(CN) 4(N3)2(C7H19N 3)2]n, is a one-dimensional heterometallic covalent chain where Ni(CN)42- functions as a molecular ion bridge. The Ni atom sits on the centre of inversion. The chain undergoes hydrogen-bonding interactions, forming a three-dimensional supramolecular network.",

author = "Debajyoti Ghoshal and Maji, \{Tapas Kumar\} and Georgina Rosair and Golam Mostafa",

year = "2004",

month = may,

doi = "10.1107/S0108270104007152",

language = "English",

volume = "60",

pages = "m212--m214",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "1600-5759",

publisher = "International Union of Crystallography",

number = "5",

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TY - JOUR

T1 - A heterometallic polymeric complex

T2 - [Cu2(N3) 2(medpt)2{Ni(CN)4}]n[medpt is bis(3-aminopropyl)methylamine]1

AU - Ghoshal, Debajyoti

AU - Maji, Tapas Kumar

AU - Rosair, Georgina

AU - Mostafa, Golam

PY - 2004/5

Y1 - 2004/5

N2 - The structure of the title compound, catena-poly[[di-µ-azido-k 4N1l:N 1-bis[[bis(3-aminopropyl)methylamine-k 3N]copper(II)]]-µ-cyano-[dicyanonickel(II)]-µ-cyano], [Cu 2(N3)2(medpt)2{Ni-(CN) 4}]n [medpt is bis(3-aminopropyl)methylamine, C 7H19-N2] or [Cu2Ni(CN) 4(N3)2(C7H19N 3)2]n, is a one-dimensional heterometallic covalent chain where Ni(CN)42- functions as a molecular ion bridge. The Ni atom sits on the centre of inversion. The chain undergoes hydrogen-bonding interactions, forming a three-dimensional supramolecular network.

AB - The structure of the title compound, catena-poly[[di-µ-azido-k 4N1l:N 1-bis[[bis(3-aminopropyl)methylamine-k 3N]copper(II)]]-µ-cyano-[dicyanonickel(II)]-µ-cyano], [Cu 2(N3)2(medpt)2{Ni-(CN) 4}]n [medpt is bis(3-aminopropyl)methylamine, C 7H19-N2] or [Cu2Ni(CN) 4(N3)2(C7H19N 3)2]n, is a one-dimensional heterometallic covalent chain where Ni(CN)42- functions as a molecular ion bridge. The Ni atom sits on the centre of inversion. The chain undergoes hydrogen-bonding interactions, forming a three-dimensional supramolecular network.

UR - https://www.scopus.com/pages/publications/2942659974

U2 - 10.1107/S0108270104007152

DO - 10.1107/S0108270104007152

M3 - Article

SN - 1600-5759

VL - 60

SP - m212-m214

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 5

ER -

A heterometallic polymeric complex: [Cu₂(N₃) ₂(medpt)₂{Ni(CN)₄}]_n[medpt is bis(3-aminopropyl)methylamine]¹

Abstract

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