TY - JOUR
T1 - A heterometallic polymeric complex
T2 - [Cu2(N3) 2(medpt)2{Ni(CN)4}]n[medpt is bis(3-aminopropyl)methylamine]1
AU - Ghoshal, Debajyoti
AU - Maji, Tapas Kumar
AU - Rosair, Georgina
AU - Mostafa, Golam
PY - 2004/5
Y1 - 2004/5
N2 - The structure of the title compound, catena-poly[[di-µ-azido-k 4N1l:N 1-bis[[bis(3-aminopropyl)methylamine-k 3N]copper(II)]]-µ-cyano-[dicyanonickel(II)]-µ-cyano], [Cu 2(N3)2(medpt)2{Ni-(CN) 4}]n [medpt is bis(3-aminopropyl)methylamine, C 7H19-N2] or [Cu2Ni(CN) 4(N3)2(C7H19N 3)2]n, is a one-dimensional heterometallic covalent chain where Ni(CN)42- functions as a molecular ion bridge. The Ni atom sits on the centre of inversion. The chain undergoes hydrogen-bonding interactions, forming a three-dimensional supramolecular network.
AB - The structure of the title compound, catena-poly[[di-µ-azido-k 4N1l:N 1-bis[[bis(3-aminopropyl)methylamine-k 3N]copper(II)]]-µ-cyano-[dicyanonickel(II)]-µ-cyano], [Cu 2(N3)2(medpt)2{Ni-(CN) 4}]n [medpt is bis(3-aminopropyl)methylamine, C 7H19-N2] or [Cu2Ni(CN) 4(N3)2(C7H19N 3)2]n, is a one-dimensional heterometallic covalent chain where Ni(CN)42- functions as a molecular ion bridge. The Ni atom sits on the centre of inversion. The chain undergoes hydrogen-bonding interactions, forming a three-dimensional supramolecular network.
UR - http://www.scopus.com/inward/record.url?scp=2942659974&partnerID=8YFLogxK
U2 - 10.1107/S0108270104007152
DO - 10.1107/S0108270104007152
M3 - Article
SN - 0108-2701
VL - 60
SP - m212-m214
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 5
ER -