A ferromagnetically coupled pseudo-calixarene [Co16] wheel that self-assembles as a tubular network of capsules

Pinelopi A. Tsami, Thomais G. Tziotzi, Angelos B. Canaj, Mukesh K. Singh, Scott J. Dalgarno, Euan K. Brechin, Constantinos J. Milios

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Abstract

Reaction of Co(OAc)2·4H2O and Hsal in a basic MeCN solution affords the hexadecanuclear wheel [Co16(sal)16(OAc)16]·16MeCN (1·16MeCN) that displays ferromagnetic nearest neighbour exchange and has pseudo-calixarene character. Symmetry equivalent wheels self-assemble to form remarkable tubular networks of capsules in the extended structure.

Original languageEnglish
Pages (from-to)15128-15132
Number of pages5
JournalDalton Transactions
Volume51
Issue number39
Early online date9 Sep 2022
DOIs
Publication statusPublished - 21 Oct 2022

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