A Catalytic Palladium Active-Metal Template Pathway to [2]Rotaxanes

José Berná, James D. Crowley, Stephen M. Goldup, Kevin D. Hänni, Ai-Lan Lee, David A. Leigh

Research output: Contribution to journalArticlepeer-review

93 Citations (Scopus)

Abstract

A multitasking template: [2]Rotaxanes have been synthesized with the help of a palladium active-metal template, which acts as both a template for threading and a catalyst for covalent-bond formation (see scheme). The synthesis is high yielding, operates under mild conditions, and is catalytic in palladium.
Original languageEnglish
Pages (from-to)5709-5713
Number of pages5
JournalAngewandte Chemie International Edition
Volume46
Issue number30
DOIs
Publication statusPublished - 23 Jul 2007

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