A Catalytic Palladium Active-Metal Template Pathway to [2]Rotaxanes

José Berná; James D. Crowley; Stephen M. Goldup; Kevin D. Hänni; Ai-Lan Lee; David A. Leigh

doi:10.1002/anie.200701678

A Catalytic Palladium Active-Metal Template Pathway to [2]Rotaxanes

José Berná, James D. Crowley, Stephen M. Goldup, Kevin D. Hänni, Ai-Lan Lee, David A. Leigh

Research output: Contribution to journal › Article › peer-review

96 Citations (Scopus)

Abstract

A multitasking template: [2]Rotaxanes have been synthesized with the help of a palladium active-metal template, which acts as both a template for threading and a catalyst for covalent-bond formation (see scheme). The synthesis is high yielding, operates under mild conditions, and is catalytic in palladium.

Original language	English
Pages (from-to)	5709-5713
Number of pages	5
Journal	Angewandte Chemie International Edition
Volume	46
Issue number	30
DOIs	https://doi.org/10.1002/anie.200701678
Publication status	Published - 23 Jul 2007

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abstract = "A multitasking template: [2]Rotaxanes have been synthesized with the help of a palladium active-metal template, which acts as both a template for threading and a catalyst for covalent-bond formation (see scheme). The synthesis is high yielding, operates under mild conditions, and is catalytic in palladium.",

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AU - Lee, Ai-Lan

AU - Leigh, David A.

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AB - A multitasking template: [2]Rotaxanes have been synthesized with the help of a palladium active-metal template, which acts as both a template for threading and a catalyst for covalent-bond formation (see scheme). The synthesis is high yielding, operates under mild conditions, and is catalytic in palladium.

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A Catalytic Palladium Active-Metal Template Pathway to [2]Rotaxanes

Abstract

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