A 1D thiocyanato bridge nickel(II) system: Crystal structure and magnetic property

Tapas Kumar Maji; Inamur Rahaman Laskar; Golam Mostafa; Alan J. Welch; Partha Sarathi Mukherjee; Nirmalendu Ray Chaudhuri

doi:10.1016/S0277-5387(01)00729-X

A 1D thiocyanato bridge nickel(II) system: Crystal structure and magnetic property

Tapas Kumar Maji, Inamur Rahaman Laskar, Golam Mostafa, Alan J. Welch, Partha Sarathi Mukherjee, Nirmalendu Ray Chaudhuri

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

A one-dimensional coordination polymer of nickel(II), [(µ_N,S-NCS)₂{Ni(ampy)}]_n (ampy = 1-(2-aminoethyl)pyrrolidine) has been synthesized and characterized by X-ray single crystal analysis. Structure analysis reveals that each nickel(II) center is coordinated in a distorted octahedral fashion with four bridging thiocyanato ligands and one mesocyclic diamine ligand. The low temperature (300-18 K) magnetic measurement shows that the system is ferromagnetically coupled. The magnetic data are fitted to the de Neef equation, giving the parameters J = 1.4 cm^-1 and g= 2.08. © 2001 Elsevier Science B.V.

Original language	English
Pages (from-to)	651-655
Number of pages	5
Journal	Polyhedron
Volume	20
Issue number	7-8
DOIs	https://doi.org/10.1016/S0277-5387(01)00729-X
Publication status	Published - 15 Apr 2001

Keywords

Crystal structures
ID polymer
Magnetic properties
Nickel(II) complexes
Thiocyanato bridge complexes

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10.1016/S0277-5387(01)00729-X

Cite this

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title = "A 1D thiocyanato bridge nickel(II) system: Crystal structure and magnetic property",

abstract = "A one-dimensional coordination polymer of nickel(II), [(µN,S-NCS)2\{Ni(ampy)\}]n (ampy = 1-(2-aminoethyl)pyrrolidine) has been synthesized and characterized by X-ray single crystal analysis. Structure analysis reveals that each nickel(II) center is coordinated in a distorted octahedral fashion with four bridging thiocyanato ligands and one mesocyclic diamine ligand. The low temperature (300-18 K) magnetic measurement shows that the system is ferromagnetically coupled. The magnetic data are fitted to the de Neef equation, giving the parameters J = 1.4 cm-1 and g= 2.08. {\textcopyright} 2001 Elsevier Science B.V.",

keywords = "Crystal structures, ID polymer, Magnetic properties, Nickel(II) complexes, Thiocyanato bridge complexes",

author = "Maji, \{Tapas Kumar\} and Laskar, \{Inamur Rahaman\} and Golam Mostafa and Welch, \{Alan J.\} and Mukherjee, \{Partha Sarathi\} and Chaudhuri, \{Nirmalendu Ray\}",

year = "2001",

month = apr,

day = "15",

doi = "10.1016/S0277-5387(01)00729-X",

language = "English",

volume = "20",

pages = "651--655",

journal = "Polyhedron",

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TY - JOUR

T1 - A 1D thiocyanato bridge nickel(II) system

T2 - Crystal structure and magnetic property

AU - Maji, Tapas Kumar

AU - Laskar, Inamur Rahaman

AU - Mostafa, Golam

AU - Welch, Alan J.

AU - Mukherjee, Partha Sarathi

AU - Chaudhuri, Nirmalendu Ray

PY - 2001/4/15

Y1 - 2001/4/15

N2 - A one-dimensional coordination polymer of nickel(II), [(µN,S-NCS)2{Ni(ampy)}]n (ampy = 1-(2-aminoethyl)pyrrolidine) has been synthesized and characterized by X-ray single crystal analysis. Structure analysis reveals that each nickel(II) center is coordinated in a distorted octahedral fashion with four bridging thiocyanato ligands and one mesocyclic diamine ligand. The low temperature (300-18 K) magnetic measurement shows that the system is ferromagnetically coupled. The magnetic data are fitted to the de Neef equation, giving the parameters J = 1.4 cm-1 and g= 2.08. © 2001 Elsevier Science B.V.

AB - A one-dimensional coordination polymer of nickel(II), [(µN,S-NCS)2{Ni(ampy)}]n (ampy = 1-(2-aminoethyl)pyrrolidine) has been synthesized and characterized by X-ray single crystal analysis. Structure analysis reveals that each nickel(II) center is coordinated in a distorted octahedral fashion with four bridging thiocyanato ligands and one mesocyclic diamine ligand. The low temperature (300-18 K) magnetic measurement shows that the system is ferromagnetically coupled. The magnetic data are fitted to the de Neef equation, giving the parameters J = 1.4 cm-1 and g= 2.08. © 2001 Elsevier Science B.V.

KW - Crystal structures

KW - ID polymer

KW - Magnetic properties

KW - Nickel(II) complexes

KW - Thiocyanato bridge complexes

UR - https://www.scopus.com/pages/publications/0035870449

U2 - 10.1016/S0277-5387(01)00729-X

DO - 10.1016/S0277-5387(01)00729-X

M3 - Article

SN - 0277-5387

VL - 20

SP - 651

EP - 655

JO - Polyhedron

JF - Polyhedron

IS - 7-8

ER -

A 1D thiocyanato bridge nickel(II) system: Crystal structure and magnetic property

Abstract

Keywords

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