TY - JOUR
T1 - A 1D thiocyanato bridge nickel(II) system
T2 - Crystal structure and magnetic property
AU - Maji, Tapas Kumar
AU - Laskar, Inamur Rahaman
AU - Mostafa, Golam
AU - Welch, Alan J.
AU - Mukherjee, Partha Sarathi
AU - Chaudhuri, Nirmalendu Ray
PY - 2001/4/15
Y1 - 2001/4/15
N2 - A one-dimensional coordination polymer of nickel(II), [(µN,S-NCS)2{Ni(ampy)}]n (ampy = 1-(2-aminoethyl)pyrrolidine) has been synthesized and characterized by X-ray single crystal analysis. Structure analysis reveals that each nickel(II) center is coordinated in a distorted octahedral fashion with four bridging thiocyanato ligands and one mesocyclic diamine ligand. The low temperature (300-18 K) magnetic measurement shows that the system is ferromagnetically coupled. The magnetic data are fitted to the de Neef equation, giving the parameters J = 1.4 cm-1 and g= 2.08. © 2001 Elsevier Science B.V.
AB - A one-dimensional coordination polymer of nickel(II), [(µN,S-NCS)2{Ni(ampy)}]n (ampy = 1-(2-aminoethyl)pyrrolidine) has been synthesized and characterized by X-ray single crystal analysis. Structure analysis reveals that each nickel(II) center is coordinated in a distorted octahedral fashion with four bridging thiocyanato ligands and one mesocyclic diamine ligand. The low temperature (300-18 K) magnetic measurement shows that the system is ferromagnetically coupled. The magnetic data are fitted to the de Neef equation, giving the parameters J = 1.4 cm-1 and g= 2.08. © 2001 Elsevier Science B.V.
KW - Crystal structures
KW - ID polymer
KW - Magnetic properties
KW - Nickel(II) complexes
KW - Thiocyanato bridge complexes
UR - http://www.scopus.com/inward/record.url?scp=0035870449&partnerID=8YFLogxK
U2 - 10.1016/S0277-5387(01)00729-X
DO - 10.1016/S0277-5387(01)00729-X
M3 - Article
SN - 0277-5387
VL - 20
SP - 651
EP - 655
JO - Polyhedron
JF - Polyhedron
IS - 7-8
ER -