A 1D thiocyanato bridge nickel(II) system: Crystal structure and magnetic property

Tapas Kumar Maji, Inamur Rahaman Laskar, Golam Mostafa, Alan J. Welch, Partha Sarathi Mukherjee, Nirmalendu Ray Chaudhuri

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

A one-dimensional coordination polymer of nickel(II), [(µN,S-NCS)2{Ni(ampy)}]n (ampy = 1-(2-aminoethyl)pyrrolidine) has been synthesized and characterized by X-ray single crystal analysis. Structure analysis reveals that each nickel(II) center is coordinated in a distorted octahedral fashion with four bridging thiocyanato ligands and one mesocyclic diamine ligand. The low temperature (300-18 K) magnetic measurement shows that the system is ferromagnetically coupled. The magnetic data are fitted to the de Neef equation, giving the parameters J = 1.4 cm-1 and g= 2.08. © 2001 Elsevier Science B.V.

Original languageEnglish
Pages (from-to)651-655
Number of pages5
JournalPolyhedron
Volume20
Issue number7-8
DOIs
Publication statusPublished - 15 Apr 2001

Keywords

  • Crystal structures
  • ID polymer
  • Magnetic properties
  • Nickel(II) complexes
  • Thiocyanato bridge complexes

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