A 15-vertex heteroborane

RD McIntosh; D Ellis; GM Rosair; AJ Welch

doi:10.1002/anie.200601266

A 15-vertex heteroborane

RD McIntosh
, D Ellis
, GM Rosair
, AJ Welch^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

109 Citations (Scopus)

Abstract

(Figure Presented) Cornering heteroboranes: The 15-vertex heteroborane 1-(p-cymene)-8,14-µ-(CH₂)₃-1,8,14-closo-RuC ₂B₁₂H₁₂ has been prepared (see structure; B orange, Ru blue, C gray). The RuC₂B₁₂ polyhedron has the form of a pentacosahedron (24 triangular faces and 1 quadrilateral face). In solution at elevated temperatures the structure is in tautomeric equilibrium by a "square-diamond-square" rearrangement involving the quadrilateral face. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

Original language	English
Pages (from-to)	4313-4316
Number of pages	4
Journal	Angewandte Chemie International Edition
Volume	45
Issue number	26
DOIs	https://doi.org/10.1002/anie.200601266
Publication status	Published - 2006

Keywords

CARBORANE
<1,1-(THF)2-COMMO-1,1'-EU(1,2,4-EUC2B10H12)2>2
structure elucidation
MOLECULAR-STRUCTURES
SUPRAICOSAHEDRAL METALLACARBORANES
STRUCTURAL-CHARACTERIZATION
CRYSTAL-STRUCTURE
TETRACARBON METALLOCARBORANES
cage compounds
carboranes
ISOMERIZATION
14-VERTEX CAGE
boron
ruthenium
COMPLEXES

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title = "A 15-vertex heteroborane",

abstract = "(Figure Presented) Cornering heteroboranes: The 15-vertex heteroborane 1-(p-cymene)-8,14-µ-(CH2)3-1,8,14-closo-RuC 2B12H12 has been prepared (see structure; B orange, Ru blue, C gray). The RuC2B12 polyhedron has the form of a pentacosahedron (24 triangular faces and 1 quadrilateral face). In solution at elevated temperatures the structure is in tautomeric equilibrium by a {"}square-diamond-square{"} rearrangement involving the quadrilateral face. {\textcopyright} 2006 Wiley-VCH Verlag GmbH \& Co. KGaA.",

keywords = "CARBORANE, <1,1-(THF)2-COMMO-1,1'-EU(1,2,4-EUC2B10H12)2>2, structure elucidation, MOLECULAR-STRUCTURES, SUPRAICOSAHEDRAL METALLACARBORANES, STRUCTURAL-CHARACTERIZATION, CRYSTAL-STRUCTURE, TETRACARBON METALLOCARBORANES, cage compounds, carboranes, ISOMERIZATION, 14-VERTEX CAGE, boron, ruthenium, COMPLEXES",

author = "RD McIntosh and D Ellis and GM Rosair and AJ Welch",

year = "2006",

doi = "10.1002/anie.200601266",

language = "English",

volume = "45",

pages = "4313--4316",

journal = "Angewandte Chemie International Edition",

issn = "1433-7851",

publisher = "Wiley",

number = "26",

}

TY - JOUR

T1 - A 15-vertex heteroborane

AU - McIntosh, RD

AU - Ellis, D

AU - Rosair, GM

AU - Welch, AJ

PY - 2006

Y1 - 2006

N2 - (Figure Presented) Cornering heteroboranes: The 15-vertex heteroborane 1-(p-cymene)-8,14-µ-(CH2)3-1,8,14-closo-RuC 2B12H12 has been prepared (see structure; B orange, Ru blue, C gray). The RuC2B12 polyhedron has the form of a pentacosahedron (24 triangular faces and 1 quadrilateral face). In solution at elevated temperatures the structure is in tautomeric equilibrium by a "square-diamond-square" rearrangement involving the quadrilateral face. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

AB - (Figure Presented) Cornering heteroboranes: The 15-vertex heteroborane 1-(p-cymene)-8,14-µ-(CH2)3-1,8,14-closo-RuC 2B12H12 has been prepared (see structure; B orange, Ru blue, C gray). The RuC2B12 polyhedron has the form of a pentacosahedron (24 triangular faces and 1 quadrilateral face). In solution at elevated temperatures the structure is in tautomeric equilibrium by a "square-diamond-square" rearrangement involving the quadrilateral face. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

KW - CARBORANE

KW - <1,1-(THF)2-COMMO-1,1'-EU(1,2,4-EUC2B10H12)2>2

KW - structure elucidation

KW - MOLECULAR-STRUCTURES

KW - SUPRAICOSAHEDRAL METALLACARBORANES

KW - STRUCTURAL-CHARACTERIZATION

KW - CRYSTAL-STRUCTURE

KW - TETRACARBON METALLOCARBORANES

KW - cage compounds

KW - carboranes

KW - ISOMERIZATION

KW - 14-VERTEX CAGE

KW - boron

KW - ruthenium

KW - COMPLEXES

U2 - 10.1002/anie.200601266

DO - 10.1002/anie.200601266

M3 - Article

SN - 1433-7851

VL - 45

SP - 4313

EP - 4316

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 26

ER -

A 15-vertex heteroborane

Abstract

Keywords

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