A 1,1'-ferrocenyl phosphine-borane: synthesis, structure and evaluation in Rh-catalyzed hydroformylation

Magnus William Paul Bebbington; Sebastien Bontemps; Ghenwa Bouhadir; Martin J Hanton; Robert P Tooze; Hendrick van Rensburg; Didier Bourissou

doi:10.1039/C0NJ00117A

A 1,1'-ferrocenyl phosphine-borane: synthesis, structure and evaluation in Rh-catalyzed hydroformylation

Magnus William Paul Bebbington, Sebastien Bontemps, Ghenwa Bouhadir, Martin J Hanton, Robert P Tooze, Hendrick van Rensburg, Didier Bourissou

Research output: Contribution to journal › Article › peer-review

42 Citations (Scopus)

Abstract

The new ambiphilic ligand Ph2P–(1,10-ferrocenyl)–BMes2, prepared by sequential lithiation/electrophilic trapping of 1,10-dibromoferrocene, adopts a monomeric structure free of dative P-B and Fe-B interactions. This flexible phosphineborane and the related o-phenylene bridged system have been evaluated in Rh-catalyzed hydroformylation.

Original language	English
Pages (from-to)	1556-1559
Number of pages	4
Journal	New Journal of Chemistry
Volume	34
Issue number	8
DOIs	https://doi.org/10.1039/C0NJ00117A
Publication status	Published - 2010

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abstract = "The new ambiphilic ligand Ph2P–(1,10-ferrocenyl)–BMes2, prepared by sequential lithiation/electrophilic trapping of 1,10-dibromoferrocene, adopts a monomeric structure free of dative P-B and Fe-B interactions. This flexible phosphineborane and the related o-phenylene bridged system have been evaluated in Rh-catalyzed hydroformylation.",

author = "Bebbington, \{Magnus William Paul\} and Sebastien Bontemps and Ghenwa Bouhadir and Hanton, \{Martin J\} and Tooze, \{Robert P\} and \{van Rensburg\}, Hendrick and Didier Bourissou",

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language = "English",

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T1 - A 1,1'-ferrocenyl phosphine-borane: synthesis, structure and evaluation in Rh-catalyzed hydroformylation

AU - Bebbington, Magnus William Paul

AU - Bontemps, Sebastien

AU - Bouhadir, Ghenwa

AU - Hanton, Martin J

AU - Tooze, Robert P

AU - van Rensburg, Hendrick

AU - Bourissou, Didier

PY - 2010

Y1 - 2010

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AB - The new ambiphilic ligand Ph2P–(1,10-ferrocenyl)–BMes2, prepared by sequential lithiation/electrophilic trapping of 1,10-dibromoferrocene, adopts a monomeric structure free of dative P-B and Fe-B interactions. This flexible phosphineborane and the related o-phenylene bridged system have been evaluated in Rh-catalyzed hydroformylation.

U2 - 10.1039/C0NJ00117A

DO - 10.1039/C0NJ00117A

M3 - Article

AN - SCOPUS:77955074093

SN - 1369-9261

VL - 34

SP - 1556

EP - 1559

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 8

ER -

A 1,1'-ferrocenyl phosphine-borane: synthesis, structure and evaluation in Rh-catalyzed hydroformylation

Abstract

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