8-[1,2-Bis(diphenylphosphino)ethane]-9,10-μ-hydrido-8-rhoda-7-thia-nido- undecaborane(10)-dichloromethane (2/1)

Georgina M. Rosair; Alan J. Welch; Andrew S. Weller

doi:10.1107/S0108270196010748

8-[1,2-Bis(diphenylphosphino)ethane]-9,10-μ-hydrido-8-rhoda-7-thia-nido- undecaborane(10)-dichloromethane (2/1)

Georgina M. Rosair, Alan J. Welch, Andrew S. Weller

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

The solid-state structure of the title compound, [Rh(B₉H₁₀S)(C₂₆H₂₄P ₂)]-0.5CH₂Cl₂, has a nido cluster geometry but, apparently, only a closo electron count. This anomaly is rationalized in terms of long range ortho-phenyl agostic C-H...Rh interactions.

Original language	English
Pages (from-to)	3020-3024
Number of pages	5
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	52
Issue number	12
DOIs	https://doi.org/10.1107/S0108270196010748
Publication status	Published - Dec 1996

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title = "8-[1,2-Bis(diphenylphosphino)ethane]-9,10-μ-hydrido-8-rhoda-7-thia-nido- undecaborane(10)-dichloromethane (2/1)",

abstract = "The solid-state structure of the title compound, [Rh(B9H10S)(C26H24P 2)]-0.5CH2Cl2, has a nido cluster geometry but, apparently, only a closo electron count. This anomaly is rationalized in terms of long range ortho-phenyl agostic C-H...Rh interactions.",

author = "Rosair, {Georgina M.} and Welch, {Alan J.} and Weller, {Andrew S.}",

year = "1996",

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doi = "10.1107/S0108270196010748",

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volume = "52",

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publisher = "International Union of Crystallography",

number = "12",

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T1 - 8-[1,2-Bis(diphenylphosphino)ethane]-9,10-μ-hydrido-8-rhoda-7-thia-nido- undecaborane(10)-dichloromethane (2/1)

AU - Rosair, Georgina M.

AU - Welch, Alan J.

AU - Weller, Andrew S.

PY - 1996/12

Y1 - 1996/12

N2 - The solid-state structure of the title compound, [Rh(B9H10S)(C26H24P 2)]-0.5CH2Cl2, has a nido cluster geometry but, apparently, only a closo electron count. This anomaly is rationalized in terms of long range ortho-phenyl agostic C-H...Rh interactions.

AB - The solid-state structure of the title compound, [Rh(B9H10S)(C26H24P 2)]-0.5CH2Cl2, has a nido cluster geometry but, apparently, only a closo electron count. This anomaly is rationalized in terms of long range ortho-phenyl agostic C-H...Rh interactions.

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U2 - 10.1107/S0108270196010748

DO - 10.1107/S0108270196010748

M3 - Article

SN - 0108-2701

VL - 52

SP - 3020

EP - 3024

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 12

ER -

8-[1,2-Bis(diphenylphosphino)ethane]-9,10-μ-hydrido-8-rhoda-7-thia-nido- undecaborane(10)-dichloromethane (2/1)

Abstract

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