8-[1,2-Bis(diphenylphosphino)ethane]-9,10-μ-hydrido-8-rhoda-7-thia-nido- undecaborane(10)-dichloromethane (2/1)

Georgina M. Rosair, Alan J. Welch, Andrew S. Weller

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

The solid-state structure of the title compound, [Rh(B9H10S)(C26H24P 2)]-0.5CH2Cl2, has a nido cluster geometry but, apparently, only a closo electron count. This anomaly is rationalized in terms of long range ortho-phenyl agostic C-H...Rh interactions.

Original languageEnglish
Pages (from-to)3020-3024
Number of pages5
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume52
Issue number12
DOIs
Publication statusPublished - Dec 1996

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