7,8-Diphenyl-9-dimethylsulfido10,11 -μ-hydro-7,8-dicarba-nidoundecaborane(9)

David Ellis; Georgina M. Rosair; Susan Robertson; Alan J. Welch

7,8-Diphenyl-9-dimethylsulfido10,11 -μ-hydro-7,8-dicarba-nidoundecaborane(9)

David Ellis
, Georgina M. Rosair
, Susan Robertson
, Alan J. Welch

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

In the title compound, C₁₆H₂₅B₉S, there are two crystallographically independent molecules, and the conformations of the phenyl and SMe₂ substituents indicate some intramolecular steric crowding. The bridging H atom is asymmetrically disposed. The title compound is a precursor to a crowded vertex-labelled nido carborane ligand important in establishing the mechanism of isomerization of icosahedral heteroboranes. © 2000 International Union of Crystallography.

Original language	English
Pages (from-to)	1399-1400
Number of pages	2
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	56
Issue number	11
Publication status	Published - 2000

Cite this

@article{7b4a872b665140fc8f85f272a7222f6a,

title = "7,8-Diphenyl-9-dimethylsulfido10,11 -μ-hydro-7,8-dicarba-nidoundecaborane(9)",

abstract = "In the title compound, C16H25B9S, there are two crystallographically independent molecules, and the conformations of the phenyl and SMe2 substituents indicate some intramolecular steric crowding. The bridging H atom is asymmetrically disposed. The title compound is a precursor to a crowded vertex-labelled nido carborane ligand important in establishing the mechanism of isomerization of icosahedral heteroboranes. {\textcopyright} 2000 International Union of Crystallography.",

author = "David Ellis and Rosair, \{Georgina M.\} and Susan Robertson and Welch, \{Alan J.\}",

year = "2000",

language = "English",

volume = "56",

pages = "1399--1400",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "11",

}

TY - JOUR

T1 - 7,8-Diphenyl-9-dimethylsulfido10,11 -μ-hydro-7,8-dicarba-nidoundecaborane(9)

AU - Ellis, David

AU - Rosair, Georgina M.

AU - Robertson, Susan

AU - Welch, Alan J.

PY - 2000

Y1 - 2000

N2 - In the title compound, C16H25B9S, there are two crystallographically independent molecules, and the conformations of the phenyl and SMe2 substituents indicate some intramolecular steric crowding. The bridging H atom is asymmetrically disposed. The title compound is a precursor to a crowded vertex-labelled nido carborane ligand important in establishing the mechanism of isomerization of icosahedral heteroboranes. © 2000 International Union of Crystallography.

AB - In the title compound, C16H25B9S, there are two crystallographically independent molecules, and the conformations of the phenyl and SMe2 substituents indicate some intramolecular steric crowding. The bridging H atom is asymmetrically disposed. The title compound is a precursor to a crowded vertex-labelled nido carborane ligand important in establishing the mechanism of isomerization of icosahedral heteroboranes. © 2000 International Union of Crystallography.

UR - https://www.scopus.com/pages/publications/0034319962

M3 - Article

SN - 0108-2701

VL - 56

SP - 1399

EP - 1400

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 11

ER -

7,8-Diphenyl-9-dimethylsulfido10,11 -μ-hydro-7,8-dicarba-nidoundecaborane(9)

Abstract

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