[5-Bromo-N-(2-carboxylatophenyl)-salicylideniminato]dimethyltin(IV)

Georgina M. Rosair, Dilip Kumar Dey, Brajagopal Samanta, Samiran Mitrac

Research output: Contribution to journalArticle

Abstract

The structure of the title dimethyltin(IV) complex, [2-(5-bromo-2-oxidobenzylideneamino)benzoato-?3 O,N,O']-dimethyltin(IV), [Sn(CH3)2(C14H8BrNO3)], features centro-symmetric dimers disposed about a central Sn2O2 core. Each Sn centre has seven-coordinate pentagonal-bipyramidal geometry, taking into account two moderately long Sn-O contacts about an inversion centre [2.679 (4) and 2.981 (4) Å]. The methyl groups are in an axial orientation.

Original languageEnglish
Pages (from-to)m266-m267
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume58
Issue number4
DOIs
Publication statusPublished - Apr 2002

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Dimers
Geometry
dimethyltin

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Rosair, Georgina M. ; Dey, Dilip Kumar ; Samanta, Brajagopal ; Mitrac, Samiran. / [5-Bromo-N-(2-carboxylatophenyl)-salicylideniminato]dimethyltin(IV). In: Acta Crystallographica Section C: Crystal Structure Communications. 2002 ; Vol. 58, No. 4. pp. m266-m267.
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[5-Bromo-N-(2-carboxylatophenyl)-salicylideniminato]dimethyltin(IV). / Rosair, Georgina M.; Dey, Dilip Kumar; Samanta, Brajagopal; Mitrac, Samiran.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 58, No. 4, 04.2002, p. m266-m267.

Research output: Contribution to journalArticle

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T1 - [5-Bromo-N-(2-carboxylatophenyl)-salicylideniminato]dimethyltin(IV)

AU - Rosair, Georgina M.

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