[5-Bromo-N-(2-carboxylatophenyl)-salicylideniminato]dimethyltin(IV)

Georgina M. Rosair; Dilip Kumar Dey; Brajagopal Samanta; Samiran Mitrac

doi:10.1107/S0108270102003530

[5-Bromo-N-(2-carboxylatophenyl)-salicylideniminato]dimethyltin(IV)

Georgina M. Rosair, Dilip Kumar Dey, Brajagopal Samanta, Samiran Mitrac

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article

11 Citations (Scopus)

Abstract

The structure of the title dimethyltin(IV) complex, [2-(5-bromo-2-oxidobenzylideneamino)benzoato-?³ O,N,O']-dimethyltin(IV), [Sn(CH₃)₂(C₁₄H₈BrNO₃)], features centro-symmetric dimers disposed about a central Sn₂O₂ core. Each Sn centre has seven-coordinate pentagonal-bipyramidal geometry, taking into account two moderately long Sn-O contacts about an inversion centre [2.679 (4) and 2.981 (4) Å]. The methyl groups are in an axial orientation.

Original language	English
Pages (from-to)	m266-m267
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	58
Issue number	4
DOIs	https://doi.org/10.1107/S0108270102003530
Publication status	Published - Apr 2002

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title = "[5-Bromo-N-(2-carboxylatophenyl)-salicylideniminato]dimethyltin(IV)",

abstract = "The structure of the title dimethyltin(IV) complex, [2-(5-bromo-2-oxidobenzylideneamino)benzoato-?3 O,N,O']-dimethyltin(IV), [Sn(CH3)2(C14H8BrNO3)], features centro-symmetric dimers disposed about a central Sn2O2 core. Each Sn centre has seven-coordinate pentagonal-bipyramidal geometry, taking into account two moderately long Sn-O contacts about an inversion centre [2.679 (4) and 2.981 (4) {\AA}]. The methyl groups are in an axial orientation.",

author = "Rosair, {Georgina M.} and Dey, {Dilip Kumar} and Brajagopal Samanta and Samiran Mitrac",

year = "2002",

month = apr,

doi = "10.1107/S0108270102003530",

language = "English",

volume = "58",

pages = "m266--m267",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "4",

}

TY - JOUR

T1 - [5-Bromo-N-(2-carboxylatophenyl)-salicylideniminato]dimethyltin(IV)

AU - Rosair, Georgina M.

AU - Dey, Dilip Kumar

AU - Samanta, Brajagopal

AU - Mitrac, Samiran

PY - 2002/4

Y1 - 2002/4

N2 - The structure of the title dimethyltin(IV) complex, [2-(5-bromo-2-oxidobenzylideneamino)benzoato-?3 O,N,O']-dimethyltin(IV), [Sn(CH3)2(C14H8BrNO3)], features centro-symmetric dimers disposed about a central Sn2O2 core. Each Sn centre has seven-coordinate pentagonal-bipyramidal geometry, taking into account two moderately long Sn-O contacts about an inversion centre [2.679 (4) and 2.981 (4) Å]. The methyl groups are in an axial orientation.

AB - The structure of the title dimethyltin(IV) complex, [2-(5-bromo-2-oxidobenzylideneamino)benzoato-?3 O,N,O']-dimethyltin(IV), [Sn(CH3)2(C14H8BrNO3)], features centro-symmetric dimers disposed about a central Sn2O2 core. Each Sn centre has seven-coordinate pentagonal-bipyramidal geometry, taking into account two moderately long Sn-O contacts about an inversion centre [2.679 (4) and 2.981 (4) Å]. The methyl groups are in an axial orientation.

UR - http://www.scopus.com/inward/record.url?scp=0036529041&partnerID=8YFLogxK

U2 - 10.1107/S0108270102003530

DO - 10.1107/S0108270102003530

M3 - Article

VL - 58

SP - m266-m267

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

IS - 4

ER -