[5-Bromo-N-(2-carboxylatophenyl)-salicylideniminato]dimethyltin(IV)

Georgina M. Rosair, Dilip Kumar Dey, Brajagopal Samanta, Samiran Mitrac

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

The structure of the title dimethyltin(IV) complex, [2-(5-bromo-2-oxidobenzylideneamino)benzoato-?3 O,N,O']-dimethyltin(IV), [Sn(CH3)2(C14H8BrNO3)], features centro-symmetric dimers disposed about a central Sn2O2 core. Each Sn centre has seven-coordinate pentagonal-bipyramidal geometry, taking into account two moderately long Sn-O contacts about an inversion centre [2.679 (4) and 2.981 (4) Å]. The methyl groups are in an axial orientation.

Original languageEnglish
Pages (from-to)m266-m267
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume58
Issue number4
DOIs
Publication statusPublished - Apr 2002

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