[5-Bromo-N-(2-carboxylatophenyl)-salicylideniminato]dimethyltin(IV)

Georgina M. Rosair; Dilip Kumar Dey; Brajagopal Samanta; Samiran Mitrac

doi:10.1107/S0108270102003530

[5-Bromo-N-(2-carboxylatophenyl)-salicylideniminato]dimethyltin(IV)

Georgina M. Rosair, Dilip Kumar Dey, Brajagopal Samanta, Samiran Mitrac

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article

11 Citations (Scopus)

Abstract

The structure of the title dimethyltin(IV) complex, [2-(5-bromo-2-oxidobenzylideneamino)benzoato-?³ O,N,O']-dimethyltin(IV), [Sn(CH₃)₂(C₁₄H₈BrNO₃)], features centro-symmetric dimers disposed about a central Sn₂O₂ core. Each Sn centre has seven-coordinate pentagonal-bipyramidal geometry, taking into account two moderately long Sn-O contacts about an inversion centre [2.679 (4) and 2.981 (4) Å]. The methyl groups are in an axial orientation.

Original language	English
Pages (from-to)	m266-m267
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	58
Issue number	4
DOIs	https://doi.org/10.1107/S0108270102003530
Publication status	Published - Apr 2002

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Rosair, G. M., Dey, D. K., Samanta, B., & Mitrac, S. (2002). [5-Bromo-N-(2-carboxylatophenyl)-salicylideniminato]dimethyltin(IV). Acta Crystallographica Section C: Crystal Structure Communications, 58(4), m266-m267. https://doi.org/10.1107/S0108270102003530

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abstract = "The structure of the title dimethyltin(IV) complex, [2-(5-bromo-2-oxidobenzylideneamino)benzoato-?3 O,N,O']-dimethyltin(IV), [Sn(CH3)2(C14H8BrNO3)], features centro-symmetric dimers disposed about a central Sn2O2 core. Each Sn centre has seven-coordinate pentagonal-bipyramidal geometry, taking into account two moderately long Sn-O contacts about an inversion centre [2.679 (4) and 2.981 (4) {\AA}]. The methyl groups are in an axial orientation.",

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T1 - [5-Bromo-N-(2-carboxylatophenyl)-salicylideniminato]dimethyltin(IV)

AU - Rosair, Georgina M.

AU - Dey, Dilip Kumar

AU - Samanta, Brajagopal

AU - Mitrac, Samiran

PY - 2002/4

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AB - The structure of the title dimethyltin(IV) complex, [2-(5-bromo-2-oxidobenzylideneamino)benzoato-?3 O,N,O']-dimethyltin(IV), [Sn(CH3)2(C14H8BrNO3)], features centro-symmetric dimers disposed about a central Sn2O2 core. Each Sn centre has seven-coordinate pentagonal-bipyramidal geometry, taking into account two moderately long Sn-O contacts about an inversion centre [2.679 (4) and 2.981 (4) Å]. The methyl groups are in an axial orientation.

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SP - m266-m267

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

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