TY - JOUR
T1 - [5-Bromo-N-(2-carboxylatophenyl)-salicylideniminato]dimethyltin(IV)
AU - Rosair, Georgina M.
AU - Dey, Dilip Kumar
AU - Samanta, Brajagopal
AU - Mitrac, Samiran
PY - 2002/4
Y1 - 2002/4
N2 - The structure of the title dimethyltin(IV) complex, [2-(5-bromo-2-oxidobenzylideneamino)benzoato-?3 O,N,O']-dimethyltin(IV), [Sn(CH3)2(C14H8BrNO3)], features centro-symmetric dimers disposed about a central Sn2O2 core. Each Sn centre has seven-coordinate pentagonal-bipyramidal geometry, taking into account two moderately long Sn-O contacts about an inversion centre [2.679 (4) and 2.981 (4) Å]. The methyl groups are in an axial orientation.
AB - The structure of the title dimethyltin(IV) complex, [2-(5-bromo-2-oxidobenzylideneamino)benzoato-?3 O,N,O']-dimethyltin(IV), [Sn(CH3)2(C14H8BrNO3)], features centro-symmetric dimers disposed about a central Sn2O2 core. Each Sn centre has seven-coordinate pentagonal-bipyramidal geometry, taking into account two moderately long Sn-O contacts about an inversion centre [2.679 (4) and 2.981 (4) Å]. The methyl groups are in an axial orientation.
UR - http://www.scopus.com/inward/record.url?scp=0036529041&partnerID=8YFLogxK
U2 - 10.1107/S0108270102003530
DO - 10.1107/S0108270102003530
M3 - Article
VL - 58
SP - m266-m267
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
SN - 0108-2701
IS - 4
ER -