Abstract
The structure of the title dimethyltin(IV) complex, [2-(5-bromo-2-oxidobenzylideneamino)benzoato-?3 O,N,O']-dimethyltin(IV), [Sn(CH3)2(C14H8BrNO3)], features centro-symmetric dimers disposed about a central Sn2O2 core. Each Sn centre has seven-coordinate pentagonal-bipyramidal geometry, taking into account two moderately long Sn-O contacts about an inversion centre [2.679 (4) and 2.981 (4) Å]. The methyl groups are in an axial orientation.
| Original language | English |
|---|---|
| Pages (from-to) | m266-m267 |
| Journal | Acta Crystallographica Section C: Crystal Structure Communications |
| Volume | 58 |
| Issue number | 4 |
| DOIs | |
| Publication status | Published - Apr 2002 |
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[5-Bromo-N-(2-carboxylatophenyl)-salicylideniminato]dimethyltin(IV). / Rosair, Georgina M.; Dey, Dilip Kumar; Samanta, Brajagopal; Mitrac, Samiran.
In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 58, No. 4, 04.2002, p. m266-m267.Research output: Contribution to journal › Article
TY - JOUR
T1 - [5-Bromo-N-(2-carboxylatophenyl)-salicylideniminato]dimethyltin(IV)
AU - Rosair, Georgina M.
AU - Dey, Dilip Kumar
AU - Samanta, Brajagopal
AU - Mitrac, Samiran
PY - 2002/4
Y1 - 2002/4
N2 - The structure of the title dimethyltin(IV) complex, [2-(5-bromo-2-oxidobenzylideneamino)benzoato-?3 O,N,O']-dimethyltin(IV), [Sn(CH3)2(C14H8BrNO3)], features centro-symmetric dimers disposed about a central Sn2O2 core. Each Sn centre has seven-coordinate pentagonal-bipyramidal geometry, taking into account two moderately long Sn-O contacts about an inversion centre [2.679 (4) and 2.981 (4) Å]. The methyl groups are in an axial orientation.
AB - The structure of the title dimethyltin(IV) complex, [2-(5-bromo-2-oxidobenzylideneamino)benzoato-?3 O,N,O']-dimethyltin(IV), [Sn(CH3)2(C14H8BrNO3)], features centro-symmetric dimers disposed about a central Sn2O2 core. Each Sn centre has seven-coordinate pentagonal-bipyramidal geometry, taking into account two moderately long Sn-O contacts about an inversion centre [2.679 (4) and 2.981 (4) Å]. The methyl groups are in an axial orientation.
UR - http://www.scopus.com/inward/record.url?scp=0036529041&partnerID=8YFLogxK
U2 - 10.1107/S0108270102003530
DO - 10.1107/S0108270102003530
M3 - Article
VL - 58
SP - m266-m267
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
SN - 0108-2701
IS - 4
ER -