3-(η3-allyl)-3,3-dicarbonyl-4-(dimethyl sulfido)-3,1,2-molybdadicarba-closo-dodecaborane(12)

Kjeld Johansen; Georgina M. Rosair; Andrew S. Weller; Alan J. Welch

3-(η³-allyl)-3,3-dicarbonyl-4-(dimethyl sulfido)-3,1,2-molybdadicarba-closo-dodecaborane(12)

Kjeld Johansen
, Georgina M. Rosair
, Andrew S. Weller
, Alan J. Welch

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

The title charge-compensated allyl carbamolybdaborane 3-(?³-C₃H₅)-3,3-(CO)₂-4-SMe ₂-3,1,2-closo-MoC₂B₉H₁₀, or [Mo(C₃H₅)(C₄H₁₆B ₉S)(CO)₂], has been synthesized and its solid-state structure determined. In the solid state, the conformation of the {Mo(?³-C₃H₅)(CO)₂} fragment is such that the carbonyl ligands are approximately trans to the cage C atoms and the conformation of the allyl group is exo.

Original language	English
Pages (from-to)	214-217
Number of pages	4
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	54
Issue number	2
Publication status	Published - 15 Feb 1998

Cite this

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title = "3-(η3-allyl)-3,3-dicarbonyl-4-(dimethyl sulfido)-3,1,2-molybdadicarba-closo-dodecaborane(12)",

abstract = "The title charge-compensated allyl carbamolybdaborane 3-(?3-C3H5)-3,3-(CO)2-4-SMe 2-3,1,2-closo-MoC2B9H10, or [Mo(C3H5)(C4H16B 9S)(CO)2], has been synthesized and its solid-state structure determined. In the solid state, the conformation of the \{Mo(?3-C3H5)(CO)2\} fragment is such that the carbonyl ligands are approximately trans to the cage C atoms and the conformation of the allyl group is exo.",

author = "Kjeld Johansen and Rosair, \{Georgina M.\} and Weller, \{Andrew S.\} and Welch, \{Alan J.\}",

year = "1998",

month = feb,

day = "15",

language = "English",

volume = "54",

pages = "214--217",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "2",

}

TY - JOUR

T1 - 3-(η3-allyl)-3,3-dicarbonyl-4-(dimethyl sulfido)-3,1,2-molybdadicarba-closo-dodecaborane(12)

AU - Johansen, Kjeld

AU - Rosair, Georgina M.

AU - Weller, Andrew S.

AU - Welch, Alan J.

PY - 1998/2/15

Y1 - 1998/2/15

N2 - The title charge-compensated allyl carbamolybdaborane 3-(?3-C3H5)-3,3-(CO)2-4-SMe 2-3,1,2-closo-MoC2B9H10, or [Mo(C3H5)(C4H16B 9S)(CO)2], has been synthesized and its solid-state structure determined. In the solid state, the conformation of the {Mo(?3-C3H5)(CO)2} fragment is such that the carbonyl ligands are approximately trans to the cage C atoms and the conformation of the allyl group is exo.

AB - The title charge-compensated allyl carbamolybdaborane 3-(?3-C3H5)-3,3-(CO)2-4-SMe 2-3,1,2-closo-MoC2B9H10, or [Mo(C3H5)(C4H16B 9S)(CO)2], has been synthesized and its solid-state structure determined. In the solid state, the conformation of the {Mo(?3-C3H5)(CO)2} fragment is such that the carbonyl ligands are approximately trans to the cage C atoms and the conformation of the allyl group is exo.

UR - https://www.scopus.com/pages/publications/0032001246

M3 - Article

SN - 0108-2701

VL - 54

SP - 214

EP - 217

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 2

ER -

3-(η³-allyl)-3,3-dicarbonyl-4-(dimethyl sulfido)-3,1,2-molybdadicarba-closo-dodecaborane(12)

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