3-(η3-allyl)-3,3-dicarbonyl-4-(dimethyl sulfido)-3,1,2-molybdadicarba-closo-dodecaborane(12)

Kjeld Johansen, Georgina M. Rosair, Andrew S. Weller, Alan J. Welch

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

The title charge-compensated allyl carbamolybdaborane 3-(?3-C3H5)-3,3-(CO)2-4-SMe 2-3,1,2-closo-MoC2B9H10, or [Mo(C3H5)(C4H16B 9S)(CO)2], has been synthesized and its solid-state structure determined. In the solid state, the conformation of the {Mo(?3-C3H5)(CO)2} fragment is such that the carbonyl ligands are approximately trans to the cage C atoms and the conformation of the allyl group is exo.

Original languageEnglish
Pages (from-to)214-217
Number of pages4
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume54
Issue number2
Publication statusPublished - 15 Feb 1998

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