2D parallel interpenetration of [M2(bpp)4X4] [M, Fe(II)/Co(II); bpp, 4,4′-trimethylenedipyridine; X, SCN-, SeCN- and N3-] complexes: Pseudohalide-dependent conformation of bpp

Subal Chandra Manna; Atish Dipankar Jana; Georgina M. Rosair; M. G B Drew; Golam Mostafa; Nirmalendu Ray Chaudhuri

doi:10.1016/j.jssc.2007.12.009

2D parallel interpenetration of [M₂(bpp)₄X₄] [M, Fe(II)/Co(II); bpp, 4,4′-trimethylenedipyridine; X, SCN^-, SeCN^- and N₃^-] complexes: Pseudohalide-dependent conformation of bpp

Subal Chandra Manna, Atish Dipankar Jana, Georgina M. Rosair, M. G B Drew, Golam Mostafa, Nirmalendu Ray Chaudhuri

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Three coordination complexes of Co(II)/Fe(II) with 4,4'-trimethylenedipyridine (bpp) and pseudohalides (SCN^-, SeCN^- and N₃^-) have been synthesized. The complexes have been characterized by X-ray single crystal structure determination. They are isomorphous having 2D layers in which two independent wavy nets display parallel interwoven structures. Pseudohalide binds metal centers through N terminal and occupies the trans axial positions of the octahedral metal coordination environment. Pseudohalide remains pendant on both sides of the polymeric layer and help the stacking through hydrogen bonding. The conformation of bpp in the interpenetrated nets is observed to be dependent on the choice of pseudohalide. © 2008 Elsevier Inc. All rights reserved.

Original language	English
Pages (from-to)	457-466
Number of pages	10
Journal	Journal of Solid State Chemistry
Volume	181
Issue number	3
DOIs	https://doi.org/10.1016/j.jssc.2007.12.009
Publication status	Published - Mar 2008

Keywords

4
4′-trimethylenedipyridine
Co(II)
Fe(II)
Interpenetration
Pseudohalide
Supramolecule

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10.1016/j.jssc.2007.12.009

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Manna, S. C., Jana, A. D., Rosair, G. M., Drew, M. G. B., Mostafa, G., & Ray Chaudhuri, N. (2008). 2D parallel interpenetration of [M₂(bpp)₄X₄] [M, Fe(II)/Co(II); bpp, 4,4′-trimethylenedipyridine; X, SCN^-, SeCN^- and N₃^-] complexes: Pseudohalide-dependent conformation of bpp. Journal of Solid State Chemistry, 181(3), 457-466. https://doi.org/10.1016/j.jssc.2007.12.009

@article{183adc5c61934a7d8ff08517e09b076b,

title = "2D parallel interpenetration of [M2(bpp)4X4] [M, Fe(II)/Co(II); bpp, 4,4′-trimethylenedipyridine; X, SCN-, SeCN- and N3-] complexes: Pseudohalide-dependent conformation of bpp",

abstract = "Three coordination complexes of Co(II)/Fe(II) with 4,4'-trimethylenedipyridine (bpp) and pseudohalides (SCN-, SeCN- and N3-) have been synthesized. The complexes have been characterized by X-ray single crystal structure determination. They are isomorphous having 2D layers in which two independent wavy nets display parallel interwoven structures. Pseudohalide binds metal centers through N terminal and occupies the trans axial positions of the octahedral metal coordination environment. Pseudohalide remains pendant on both sides of the polymeric layer and help the stacking through hydrogen bonding. The conformation of bpp in the interpenetrated nets is observed to be dependent on the choice of pseudohalide. {\textcopyright} 2008 Elsevier Inc. All rights reserved.",

keywords = "4, 4′-trimethylenedipyridine, Co(II), Fe(II), Interpenetration, Pseudohalide, Supramolecule",

author = "Manna, {Subal Chandra} and Jana, {Atish Dipankar} and Rosair, {Georgina M.} and Drew, {M. G B} and Golam Mostafa and {Ray Chaudhuri}, Nirmalendu",

year = "2008",

month = mar,

doi = "10.1016/j.jssc.2007.12.009",

language = "English",

volume = "181",

pages = "457--466",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

number = "3",

}

2D parallel interpenetration of [M₂(bpp)₄X₄] [M, Fe(II)/Co(II); bpp, 4,4′-trimethylenedipyridine; X, SCN^-, SeCN^- and N₃^-] complexes: Pseudohalide-dependent conformation of bpp. / Manna, Subal Chandra; Jana, Atish Dipankar; Rosair, Georgina M. et al.
In: Journal of Solid State Chemistry, Vol. 181, No. 3, 03.2008, p. 457-466.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - 2D parallel interpenetration of [M2(bpp)4X4] [M, Fe(II)/Co(II); bpp, 4,4′-trimethylenedipyridine; X, SCN-, SeCN- and N3-] complexes

T2 - Pseudohalide-dependent conformation of bpp

AU - Manna, Subal Chandra

AU - Jana, Atish Dipankar

AU - Rosair, Georgina M.

AU - Drew, M. G B

AU - Mostafa, Golam

AU - Ray Chaudhuri, Nirmalendu

PY - 2008/3

Y1 - 2008/3

N2 - Three coordination complexes of Co(II)/Fe(II) with 4,4'-trimethylenedipyridine (bpp) and pseudohalides (SCN-, SeCN- and N3-) have been synthesized. The complexes have been characterized by X-ray single crystal structure determination. They are isomorphous having 2D layers in which two independent wavy nets display parallel interwoven structures. Pseudohalide binds metal centers through N terminal and occupies the trans axial positions of the octahedral metal coordination environment. Pseudohalide remains pendant on both sides of the polymeric layer and help the stacking through hydrogen bonding. The conformation of bpp in the interpenetrated nets is observed to be dependent on the choice of pseudohalide. © 2008 Elsevier Inc. All rights reserved.

AB - Three coordination complexes of Co(II)/Fe(II) with 4,4'-trimethylenedipyridine (bpp) and pseudohalides (SCN-, SeCN- and N3-) have been synthesized. The complexes have been characterized by X-ray single crystal structure determination. They are isomorphous having 2D layers in which two independent wavy nets display parallel interwoven structures. Pseudohalide binds metal centers through N terminal and occupies the trans axial positions of the octahedral metal coordination environment. Pseudohalide remains pendant on both sides of the polymeric layer and help the stacking through hydrogen bonding. The conformation of bpp in the interpenetrated nets is observed to be dependent on the choice of pseudohalide. © 2008 Elsevier Inc. All rights reserved.

KW - 4

KW - 4′-trimethylenedipyridine

KW - Co(II)

KW - Fe(II)

KW - Interpenetration

KW - Pseudohalide

KW - Supramolecule

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U2 - 10.1016/j.jssc.2007.12.009

DO - 10.1016/j.jssc.2007.12.009

M3 - Article

SN - 0022-4596

VL - 181

SP - 457

EP - 466

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 3

ER -

2D parallel interpenetration of [M₂(bpp)₄X₄] [M, Fe(II)/Co(II); bpp, 4,4′-trimethylenedipyridine; X, SCN^-, SeCN^- and N₃^-] complexes: Pseudohalide-dependent conformation of bpp

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