1269. Preparation and reactions of vinyl radicals

N A Weir

Research output: Contribution to journalArticle

Abstract

Vinyl radicals have been prepared by the methyl-radical sensitised decompositions of acraldehyde and vinyl formate; attempts to obtain the radicals directly by photolyses of acraldehyde and divinylmercury were unsuccessful. Ratios of rate constants (?) for like- and cross-disproportionation to like-and cross-combination, determined at 175°, are: ?(Vinyl, Vinyl)= 1-1, ?(Me, Vinyl)=2-3.

Original languageEnglish
Pages (from-to)6870-6872
Number of pages3
JournalJournal of the Chemical Society (Resumed)
DOIs
Publication statusPublished - 1965

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Acrolein
formic acid
Photolysis
Rate constants
Decomposition
methyl radical

Cite this

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title = "1269. Preparation and reactions of vinyl radicals",
abstract = "Vinyl radicals have been prepared by the methyl-radical sensitised decompositions of acraldehyde and vinyl formate; attempts to obtain the radicals directly by photolyses of acraldehyde and divinylmercury were unsuccessful. Ratios of rate constants (?) for like- and cross-disproportionation to like-and cross-combination, determined at 175°, are: ?(Vinyl, Vinyl)= 1-1, ?(Me, Vinyl)=2-3.",
author = "Weir, {N A}",
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language = "English",
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}

1269. Preparation and reactions of vinyl radicals. / Weir, N A.

In: Journal of the Chemical Society (Resumed), 1965, p. 6870-6872.

Research output: Contribution to journalArticle

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AU - Weir, N A

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AB - Vinyl radicals have been prepared by the methyl-radical sensitised decompositions of acraldehyde and vinyl formate; attempts to obtain the radicals directly by photolyses of acraldehyde and divinylmercury were unsuccessful. Ratios of rate constants (?) for like- and cross-disproportionation to like-and cross-combination, determined at 175°, are: ?(Vinyl, Vinyl)= 1-1, ?(Me, Vinyl)=2-3.

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DO - 10.1039/JR9650006870

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JO - Journal of the Chemical Society (Resumed)

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