1-Diphenylphosphino-2-phenyl-1,2-dicarba-closo-dodecaborane(12)

M. Anna McWhannell; Georgina M. Rosair; Alan J. Welch; Francesc Teixidor; Clara Vinas

doi:10.1107/S0108270196009109

1-Diphenylphosphino-2-phenyl-1,2-dicarba-closo-dodecaborane(12)

M. Anna McWhannell
, Georgina M. Rosair
, Alan J. Welch
, Francesc Teixidor
, Clara Vinas

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

The two crystallographically independent molecules of the title compound, 1-[(C₆H₅)₂P]-2-C₆H ₅-1,2-C₂B₁₀H₁₀ (C₂₀H₂₅B₁₀P), in the asymmetric fraction of the unit cell are highly congruent. The conformation of the cage phenyl groups is denned by ? = 1.15° and the average C1-C2 distance is 1.744 (8) Å, which is significantly longer than that usually found for 1,2-C₂B₁₀H₁₀ compounds. The PPh₂ substituent is tilted away from an idealized radial position on C1 as a result of intramolecular crowding.

Original language	English
Pages (from-to)	3135-3138
Number of pages	4
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	52
Issue number	12
DOIs	https://doi.org/10.1107/S0108270196009109
Publication status	Published - Dec 1996

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@article{658e138316c94de188144dd2e28536d7,

title = "1-Diphenylphosphino-2-phenyl-1,2-dicarba-closo-dodecaborane(12)",

abstract = "The two crystallographically independent molecules of the title compound, 1-[(C6H5)2P]-2-C6H 5-1,2-C2B10H10 (C20H25B10P), in the asymmetric fraction of the unit cell are highly congruent. The conformation of the cage phenyl groups is denned by ? = 1.15° and the average C1-C2 distance is 1.744 (8) {\AA}, which is significantly longer than that usually found for 1,2-C2B10H10 compounds. The PPh2 substituent is tilted away from an idealized radial position on C1 as a result of intramolecular crowding.",

author = "McWhannell, \{M. Anna\} and Rosair, \{Georgina M.\} and Welch, \{Alan J.\} and Francesc Teixidor and Clara Vinas",

year = "1996",

month = dec,

doi = "10.1107/S0108270196009109",

language = "English",

volume = "52",

pages = "3135--3138",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "12",

}

TY - JOUR

T1 - 1-Diphenylphosphino-2-phenyl-1,2-dicarba-closo-dodecaborane(12)

AU - McWhannell, M. Anna

AU - Rosair, Georgina M.

AU - Welch, Alan J.

AU - Teixidor, Francesc

AU - Vinas, Clara

PY - 1996/12

Y1 - 1996/12

N2 - The two crystallographically independent molecules of the title compound, 1-[(C6H5)2P]-2-C6H 5-1,2-C2B10H10 (C20H25B10P), in the asymmetric fraction of the unit cell are highly congruent. The conformation of the cage phenyl groups is denned by ? = 1.15° and the average C1-C2 distance is 1.744 (8) Å, which is significantly longer than that usually found for 1,2-C2B10H10 compounds. The PPh2 substituent is tilted away from an idealized radial position on C1 as a result of intramolecular crowding.

AB - The two crystallographically independent molecules of the title compound, 1-[(C6H5)2P]-2-C6H 5-1,2-C2B10H10 (C20H25B10P), in the asymmetric fraction of the unit cell are highly congruent. The conformation of the cage phenyl groups is denned by ? = 1.15° and the average C1-C2 distance is 1.744 (8) Å, which is significantly longer than that usually found for 1,2-C2B10H10 compounds. The PPh2 substituent is tilted away from an idealized radial position on C1 as a result of intramolecular crowding.

UR - https://www.scopus.com/pages/publications/0030400832

U2 - 10.1107/S0108270196009109

DO - 10.1107/S0108270196009109

M3 - Article

SN - 0108-2701

VL - 52

SP - 3135

EP - 3138

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 12

ER -

1-Diphenylphosphino-2-phenyl-1,2-dicarba-closo-dodecaborane(12)

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