1-[Chloro(diphenylphosphino)gold(I)-P]-2-phenyl-1,2-dicarba-closo-dodecaborane(12)

M. A. McWhannel; Georgina Margaret Rosair; Alan Jeffrey Welch

doi:10.1107/S0108270197013048

1-[Chloro(diphenylphosphino)gold(I)-P]-2-phenyl-1,2-dicarba-closo-dodecaborane(12)

M. A. McWhannel, Georgina Margaret Rosair, Alan Jeffrey Welch

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

The title compound 1-[(C₆H₅)₂PAuCl]-2-(C₆H ₅)-1,2-closo-C₂B₁₀H₁₀ or [AuCl{(C₆H₅)₂P(C₈H ₁₅B₁₀)}], is the first reported derivative of 1-[(C₆H₅)2P]-2-(C₆H ₅)1,2-closo-C₂B₁₀H₁₀. The conformation of the cage phenyl group is comparable with the parent carbaborylphosphine, however, the (C₆H₅)₂PAuCl substituent is less tilted from an idealized radial position on C1 due to a balance between two opposing sets of intramolecular forces. The P - Au - Cl fragment adopts the expected linear geometry.

Original language	English
Pages (from-to)	13-15
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	54
Issue number	1
DOIs	https://doi.org/10.1107/S0108270197013048
Publication status	Published - Jan 1998

ASJC Scopus subject areas

Structural Biology
Condensed Matter Physics

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title = "1-[Chloro(diphenylphosphino)gold(I)-P]-2-phenyl-1,2-dicarba-closo-dodecaborane(12)",

abstract = "The title compound 1-[(C6H5)2PAuCl]-2-(C6H 5)-1,2-closo-C2B10H10 or [AuCl\{(C6H5)2P(C8H 15B10)\}], is the first reported derivative of 1-[(C6H5)2P]-2-(C6H 5)1,2-closo-C2B10H10. The conformation of the cage phenyl group is comparable with the parent carbaborylphosphine, however, the (C6H5)2PAuCl substituent is less tilted from an idealized radial position on C1 due to a balance between two opposing sets of intramolecular forces. The P - Au - Cl fragment adopts the expected linear geometry.",

author = "McWhannel, \{M. A.\} and Rosair, \{Georgina Margaret\} and Welch, \{Alan Jeffrey\}",

year = "1998",

month = jan,

doi = "10.1107/S0108270197013048",

language = "English",

volume = "54",

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T1 - 1-[Chloro(diphenylphosphino)gold(I)-P]-2-phenyl-1,2-dicarba-closo-dodecaborane(12)

AU - McWhannel, M. A.

AU - Rosair, Georgina Margaret

AU - Welch, Alan Jeffrey

PY - 1998/1

Y1 - 1998/1

N2 - The title compound 1-[(C6H5)2PAuCl]-2-(C6H 5)-1,2-closo-C2B10H10 or [AuCl{(C6H5)2P(C8H 15B10)}], is the first reported derivative of 1-[(C6H5)2P]-2-(C6H 5)1,2-closo-C2B10H10. The conformation of the cage phenyl group is comparable with the parent carbaborylphosphine, however, the (C6H5)2PAuCl substituent is less tilted from an idealized radial position on C1 due to a balance between two opposing sets of intramolecular forces. The P - Au - Cl fragment adopts the expected linear geometry.

AB - The title compound 1-[(C6H5)2PAuCl]-2-(C6H 5)-1,2-closo-C2B10H10 or [AuCl{(C6H5)2P(C8H 15B10)}], is the first reported derivative of 1-[(C6H5)2P]-2-(C6H 5)1,2-closo-C2B10H10. The conformation of the cage phenyl group is comparable with the parent carbaborylphosphine, however, the (C6H5)2PAuCl substituent is less tilted from an idealized radial position on C1 due to a balance between two opposing sets of intramolecular forces. The P - Au - Cl fragment adopts the expected linear geometry.

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DO - 10.1107/S0108270197013048

M3 - Article

SN - 0108-2701

VL - 54

SP - 13

EP - 15

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 1

ER -

1-[Chloro(diphenylphosphino)gold(I)-P]-2-phenyl-1,2-dicarba-closo-dodecaborane(12)

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