1-[Chloro(diphenylphosphino)gold(I)-P]-2-phenyl-1,2-dicarba-closo-dodecaborane(12)

M. A. McWhannel, Georgina Margaret Rosair, Alan Jeffrey Welch

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

The title compound 1-[(C6H5)2PAuCl]-2-(C6H 5)-1,2-closo-C2B10H10 or [AuCl{(C6H5)2P(C8H 15B10)}], is the first reported derivative of 1-[(C6H5)2P]-2-(C6H 5)1,2-closo-C2B10H10. The conformation of the cage phenyl group is comparable with the parent carbaborylphosphine, however, the (C6H5)2PAuCl substituent is less tilted from an idealized radial position on C1 due to a balance between two opposing sets of intramolecular forces. The P - Au - Cl fragment adopts the expected linear geometry.

Original languageEnglish
Pages (from-to)13-15
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume54
Issue number1
DOIs
Publication statusPublished - Jan 1998

ASJC Scopus subject areas

  • Structural Biology
  • Condensed Matter Physics

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