5-cyclopentadienyl)(N,N-dimethyldithiocarbamato- κ2S,S′)[η4-tetrakis-(trifluoromethyl) cyclobutadienyl]-molybdenum(IV)

Jack L. Davidson, Alice Jarvie, Kenneth W. Muir

Research output: Contribution to journalArticle

Abstract

The title complex, [Mo(C8F12)(C5H 5)(C3H6NS2)], contains both a ?4-C4(CF3)4 cyclobutadienyl ligand with approximate C4v local symmetry and a ?5- C4H5 cyclopentadienyl ring. The centroids of the rings and the S atoms of a chelating dithiocarbamate ligand define the pseudo-tetrahedral coordination of the Mo atom. The Mo-C(cyclobutadienyl) bond lengths [2.189 (2)-2.211 (2) Å] are unusually short, probably reflecting strong electron withdrawal by the trifluoromethyl groups. The molecules straddle crystallographic mirror planes. © 2005 International Union of Crystallography.

Original languageEnglish
Pages (from-to)m209-m210
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume61
Issue number4
DOIs
Publication statusPublished - Apr 2005

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Molybdenum
Ligands
Atoms
Crystallography
Bond length
Chelation
Mirrors
Molecules
Electrons

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@article{b443f9dbe496474fb6f6d7ae36036bbe,
title = "(η5-cyclopentadienyl)(N,N-dimethyldithiocarbamato- κ2S,S′)[η4-tetrakis-(trifluoromethyl) cyclobutadienyl]-molybdenum(IV)",
abstract = "The title complex, [Mo(C8F12)(C5H 5)(C3H6NS2)], contains both a ?4-C4(CF3)4 cyclobutadienyl ligand with approximate C4v local symmetry and a ?5- C4H5 cyclopentadienyl ring. The centroids of the rings and the S atoms of a chelating dithiocarbamate ligand define the pseudo-tetrahedral coordination of the Mo atom. The Mo-C(cyclobutadienyl) bond lengths [2.189 (2)-2.211 (2) {\AA}] are unusually short, probably reflecting strong electron withdrawal by the trifluoromethyl groups. The molecules straddle crystallographic mirror planes. {\circledC} 2005 International Union of Crystallography.",
author = "Davidson, {Jack L.} and Alice Jarvie and Muir, {Kenneth W.}",
year = "2005",
month = "4",
doi = "10.1107/S0108270105006086",
language = "English",
volume = "61",
pages = "m209--m210",
journal = "Acta Crystallographica Section C: Crystal Structure Communications",
issn = "0108-2701",
publisher = "International Union of Crystallography",
number = "4",

}

5-cyclopentadienyl)(N,N-dimethyldithiocarbamato- κ2S,S′)[η4-tetrakis-(trifluoromethyl) cyclobutadienyl]-molybdenum(IV). / Davidson, Jack L.; Jarvie, Alice; Muir, Kenneth W.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 61, No. 4, 04.2005, p. m209-m210.

Research output: Contribution to journalArticle

TY - JOUR

T1 - (η5-cyclopentadienyl)(N,N-dimethyldithiocarbamato- κ2S,S′)[η4-tetrakis-(trifluoromethyl) cyclobutadienyl]-molybdenum(IV)

AU - Davidson, Jack L.

AU - Jarvie, Alice

AU - Muir, Kenneth W.

PY - 2005/4

Y1 - 2005/4

N2 - The title complex, [Mo(C8F12)(C5H 5)(C3H6NS2)], contains both a ?4-C4(CF3)4 cyclobutadienyl ligand with approximate C4v local symmetry and a ?5- C4H5 cyclopentadienyl ring. The centroids of the rings and the S atoms of a chelating dithiocarbamate ligand define the pseudo-tetrahedral coordination of the Mo atom. The Mo-C(cyclobutadienyl) bond lengths [2.189 (2)-2.211 (2) Å] are unusually short, probably reflecting strong electron withdrawal by the trifluoromethyl groups. The molecules straddle crystallographic mirror planes. © 2005 International Union of Crystallography.

AB - The title complex, [Mo(C8F12)(C5H 5)(C3H6NS2)], contains both a ?4-C4(CF3)4 cyclobutadienyl ligand with approximate C4v local symmetry and a ?5- C4H5 cyclopentadienyl ring. The centroids of the rings and the S atoms of a chelating dithiocarbamate ligand define the pseudo-tetrahedral coordination of the Mo atom. The Mo-C(cyclobutadienyl) bond lengths [2.189 (2)-2.211 (2) Å] are unusually short, probably reflecting strong electron withdrawal by the trifluoromethyl groups. The molecules straddle crystallographic mirror planes. © 2005 International Union of Crystallography.

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U2 - 10.1107/S0108270105006086

DO - 10.1107/S0108270105006086

M3 - Article

VL - 61

SP - m209-m210

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

IS - 4

ER -