(η5-cyclopentadienyl)(N,N-dimethyldithiocarbamato- κ2S,S′)[η4-tetrakis-(trifluoromethyl) cyclobutadienyl]-molybdenum(IV)

Jack L. Davidson; Alice Jarvie; Kenneth W. Muir

doi:10.1107/S0108270105006086

(η⁵-cyclopentadienyl)(N,N-dimethyldithiocarbamato- κ²S,S′)[η⁴-tetrakis-(trifluoromethyl) cyclobutadienyl]-molybdenum(IV)

Jack L. Davidson, Alice Jarvie, Kenneth W. Muir

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

The title complex, [Mo(C₈F₁₂)(C₅H ₅)(C₃H₆NS₂)], contains both a ?⁴-C₄(CF₃)₄ cyclobutadienyl ligand with approximate C_4v local symmetry and a ?⁵- C₄H₅ cyclopentadienyl ring. The centroids of the rings and the S atoms of a chelating dithiocarbamate ligand define the pseudo-tetrahedral coordination of the Mo atom. The Mo-C(cyclobutadienyl) bond lengths [2.189 (2)-2.211 (2) Å] are unusually short, probably reflecting strong electron withdrawal by the trifluoromethyl groups. The molecules straddle crystallographic mirror planes. © 2005 International Union of Crystallography.

Original language	English
Pages (from-to)	m209-m210
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	61
Issue number	4
DOIs	https://doi.org/10.1107/S0108270105006086
Publication status	Published - Apr 2005

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title = "(η5-cyclopentadienyl)(N,N-dimethyldithiocarbamato- κ2S,S′)[η4-tetrakis-(trifluoromethyl) cyclobutadienyl]-molybdenum(IV)",

abstract = "The title complex, [Mo(C8F12)(C5H 5)(C3H6NS2)], contains both a ?4-C4(CF3)4 cyclobutadienyl ligand with approximate C4v local symmetry and a ?5- C4H5 cyclopentadienyl ring. The centroids of the rings and the S atoms of a chelating dithiocarbamate ligand define the pseudo-tetrahedral coordination of the Mo atom. The Mo-C(cyclobutadienyl) bond lengths [2.189 (2)-2.211 (2) {\AA}] are unusually short, probably reflecting strong electron withdrawal by the trifluoromethyl groups. The molecules straddle crystallographic mirror planes. {\textcopyright} 2005 International Union of Crystallography.",

author = "Davidson, {Jack L.} and Alice Jarvie and Muir, {Kenneth W.}",

year = "2005",

month = apr,

doi = "10.1107/S0108270105006086",

language = "English",

volume = "61",

pages = "m209--m210",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "4",

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TY - JOUR

T1 - (η5-cyclopentadienyl)(N,N-dimethyldithiocarbamato- κ2S,S′)[η4-tetrakis-(trifluoromethyl) cyclobutadienyl]-molybdenum(IV)

AU - Davidson, Jack L.

AU - Jarvie, Alice

AU - Muir, Kenneth W.

PY - 2005/4

Y1 - 2005/4

N2 - The title complex, [Mo(C8F12)(C5H 5)(C3H6NS2)], contains both a ?4-C4(CF3)4 cyclobutadienyl ligand with approximate C4v local symmetry and a ?5- C4H5 cyclopentadienyl ring. The centroids of the rings and the S atoms of a chelating dithiocarbamate ligand define the pseudo-tetrahedral coordination of the Mo atom. The Mo-C(cyclobutadienyl) bond lengths [2.189 (2)-2.211 (2) Å] are unusually short, probably reflecting strong electron withdrawal by the trifluoromethyl groups. The molecules straddle crystallographic mirror planes. © 2005 International Union of Crystallography.

AB - The title complex, [Mo(C8F12)(C5H 5)(C3H6NS2)], contains both a ?4-C4(CF3)4 cyclobutadienyl ligand with approximate C4v local symmetry and a ?5- C4H5 cyclopentadienyl ring. The centroids of the rings and the S atoms of a chelating dithiocarbamate ligand define the pseudo-tetrahedral coordination of the Mo atom. The Mo-C(cyclobutadienyl) bond lengths [2.189 (2)-2.211 (2) Å] are unusually short, probably reflecting strong electron withdrawal by the trifluoromethyl groups. The molecules straddle crystallographic mirror planes. © 2005 International Union of Crystallography.

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U2 - 10.1107/S0108270105006086

DO - 10.1107/S0108270105006086

M3 - Article

SN - 0108-2701

VL - 61

SP - m209-m210

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 4

ER -

(η⁵-cyclopentadienyl)(N,N-dimethyldithiocarbamato- κ²S,S′)[η⁴-tetrakis-(trifluoromethyl) cyclobutadienyl]-molybdenum(IV)

Abstract

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