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Personal profile

Research interests

My research focuses on the synthesis and development of new homogeneous catalysts. I use skills in synthetic main group chemistry to construct new ligands that include cooperative reaction sites to increase the potential for exciting new reactivity. Synthetic organometallic chemistry is exploited to form new transition metal and f-element catalysts for testing in challenging reactions such as dehydrocoupling and the catalytic functionalisation of dinitrogen.

Biography

Stephen started his undergraduate degree in 2001 at Imperial College London and graduated in 2005 working with Prof. Mike Hill for his MSci project on chiral ligands for enantioselective lanthanide catalysis, and winning the H.V.A. Briscoe prize for excellence in Inorganic Chemistry. In 2005 he moved to The University of Bristol and graduated in 2009 with a PhD under the joint supervision of Dr Chris Russell and Prof. Duncan Wass working on low valent and low coordination chemistry in the main group elements, with particular emphasis on developing new ligands for transition metals. He then undertook a one year post-doctoral position with Prof. Nick Norman researching boron-nitrogen analogues of polycyclic aromatic hydrocarbons. In 2010 he moved to The University of Edinburgh undertaking research on small molecule activation using highly reactive uranium centres in the group of Prof. Polly Arnold. In 2013 he worked with Prof. Paul Raithby, Prof. Chick Wilson and Dr Andy Burrows at The University of Bath in a multi-disciplinary project on meta-stable functional materials before being appointed Lecturer at Heriot-Watt University in September 2013.

Key Research Words/Phrases

Homogeneous catalysis

Cooperative reactivity

Ligand design

Main group chemistry

Phosphorus

Boron

Keywords

  • QD Chemistry
  • Inorganic
  • Catalysis

Fingerprint Dive into the research topics where Stephen M. Mansell is active. These topic labels come from the works of this person. Together they form a unique fingerprint.

Ligands Chemical Compounds
Amides Chemical Compounds
Chelation Chemical Compounds
ethylenediamine Chemical Compounds
Uranium Chemical Compounds
Salts Chemical Compounds
Deprotonation Chemical Compounds
Alkali Metals Chemical Compounds

Co Author Network Recent external collaboration on country level. Dive into details by clicking on the dots.

Research Output 2006 2020

An indenide-tethered N-heterocyclic stannylene

Bischof, T., Evans, K., Haddow, M. & Mansell, S. M., 14 Jan 2020, (Accepted/In press) In : Acta Crystallographica Section E: Crystallographic Communications.

Research output: Contribution to journalArticle

Ligands
Derivatives

Lithium Complexes with Bridging and Terminal NHC ligands: The Decisive Influence of an Anionic Tether

Evans, K. J., Campbell, C. L., Haddow, M. F., Luz, C., Morton, P. A. & Mansell, S. M., 15 Dec 2019, In : European Journal of Inorganic Chemistry. 2019, 46, p. 4894–4901 8 p.

Research output: Contribution to journalArticle

Open Access
File
Lithium
Deprotonation
Ligands
Salts
Amides

On the Basicity of Carboranylphosphines

Benton, A., Durand, D. J., Copeland, Z., Watson, J. D., Fey, N., Mansell, S. M., Rosair, G. M. & Welch, A. J., 4 Nov 2019, In : Inorganic Chemistry. 58, 21, p. 14818-14829 12 p.

Research output: Contribution to journalArticle

Open Access
File
ethylenediamine
Carbamates
Salts
Epoxy Compounds
Carbon Dioxide
Open Access
File

Datasets

Activities 2015 2019

Bathgate STEM Speeddate

Stephen M. Mansell (Invited speaker)
19 Nov 2019

Activity: Participating in or organising an eventParticipation in workshop, seminar, course

External examiner for a PhD thesis

Stephen M. Mansell (Examiner)
17 May 2019

Activity: ExaminationExternal Examiner

A Periodic Tale: 150 Years and still up to date

Stephen M. Mansell (Invited speaker)
28 May 2019

Activity: Participating in or organising an eventParticipation in workshop, seminar, course

Primary School Periodic Table Competition

Stephen M. Mansell (Organiser), Mairi Haddow (Organiser), Martin R. S. McCoustra (Reviewer), Arno Manfred Kraft (Reviewer)
17 Nov 201923 Nov 2019

Activity: Other

External examiner for a PhD thesis

Stephen M. Mansell (Examiner)
25 Jan 2019

Activity: ExaminationExternal Examiner

Press / Media