Personal profile

Research interests

Research in the group addresses several aspects of heteroborane chemistry.  In general terms we are involved with the synthesis of new heteroborane compounds, particularly metallacarboranes, in their spectroscopic and structural characterisation and in studies of their isomerisations and reactivity.  Specific areas of current interest include (but are not limited to) the chemistry of supraicosahedral heteroboranes, bis(carboranes), nitrosocarboranes and non-Wadian metallacarboranes.  We also have an interest in identifying and understanding aspects of heteroborane structure which we address both experimentally (via the synthesis and study of new compounds) and by analysing established structures in the Cambridge Structural Database.

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Research Output 1983 2017

Balancing Steric and Electronic Effects in Carbonyl-Phosphine Molybdacarboranes

Robertson, A., Reckziegel, A., Jones, J., Rosair, G. M. & Welch, A. J. 22 May 2017 In : European Journal of Inorganic Chemistry.

Research output: Contribution to journalArticle

phosphines
electronics

Double deboronation and homometalation of 1,1'-bis(ortho-carborane)

Thiripuranathar, G., Chan, A., Mandal, D., Man, W., Argentari, M., Rosair, G. M. & Welch, A. J. 14 Feb 2017 In : Dalton Transactions. 46, 6, p. 1811-1821 11 p.

Research output: Contribution to journalArticle

carborane
oxidation
Oxidation
Electrons
isomerization

Large, weakly basic bis(carboranyl)phosphines: an experimental and computational study

Riley, L. E., Krämer, T., McMullin, C. L., Ellis, D., Rosair, G. M., Sivaev, I. & Welch, A. J. 28 Apr 2017 In : Dalton Transactions. 46, 16, p. 5218-5228 11 p.

Research output: Contribution to journalArticle

Discrete Fourier transforms
Cones
Ion exchange
Protons
Derivatives

What Can We Learn from the Crystal Structures of Metallacarboranes?

Welch, A. J. Aug 2017 In : Crystals. 7, 8, 19 p., 234

Research output: Contribution to journalArticle

Cytochrome c Group
crystal structure
Crystal structure

14-Vertex Heteroboranes with 14 Skeletal Electron Pairs: An Experimental and Computational Study

Robertson, A., Beattie, N., Scott, G., Man, W., Jones, J., Macgregor, S. A., Rosair, G. M. & Welch, A. J. 18 Jul 2016 In : Angewandte Chemie International Edition. 55, 30, p. 8706-8710 5 p.

Research output: Contribution to journalArticle

electron

Prizes

Fellow of the Royal Society of Edinburgh

Alan Jeffrey Welch (Recipient), 2004

Prize: Election to learned society